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Dibromodifluoromethane

Names

[ CAS No. ]:
75-61-6

[ Name ]:
Dibromodifluoromethane

[Synonym ]:
Dibromo(difluoro)methane
Fluorocarbon 12-B2
Dibromodifluoromethane
Freon 12-B2
F 12B2
Methane,dibromodifluoro
Halon 1202
Difluorodibromomethane
Carbon dibromide difluoride
dibromo-difluoromethane
MFCD00000367
Methane, dibromodifluoro-
Freon 12B2
EINECS 200-885-5

Chemical & Physical Properties

[ Density]:
2.5±0.1 g/cm3

[ Boiling Point ]:
26.4±8.0 °C at 760 mmHg

[ Melting Point ]:
-141 °C

[ Molecular Formula ]:
CBr2F2

[ Molecular Weight ]:
209.816

[ Flash Point ]:
-30.3±18.4 °C

[ Exact Mass ]:
207.833466

[ LogP ]:
2.46

[ Vapour Pressure ]:
723.8±0.1 mmHg at 25°C

[ Index of Refraction ]:
1.457

MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
PA7525000
CHEMICAL NAME :
Methane, dibromodifluoro-
CAS REGISTRY NUMBER :
75-61-6
BEILSTEIN REFERENCE NO. :
1732515
LAST UPDATED :
199712
DATA ITEMS CITED :
28
MOLECULAR FORMULA :
C-Br2-F2
MOLECULAR WEIGHT :
209.83
WISWESSER LINE NOTATION :
FXFEE

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE :
Inhalation
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
140 gm/m3/2H
REFERENCE :
TLSMA6 Trudy Leningradskogo Sanitarno-Gigienicheskogo Meditsinskogo Instituta. (Leningrad, Russia) V.1-145, 1949-82. Discontinued. Volume(issue)/page/year: 111,10,1975 *** REVIEWS *** ACGIH TLV-TWA 858 mg/m3 (100 ppm) DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: TLV/BEI,1997 *** U.S. STANDARDS AND REGULATIONS *** MSHA STANDARD-air:TWA 100 ppm (860 mg/m3) DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: 3,86,1971 OSHA PEL (Gen Indu):8H TWA 100 ppm (860 mg/m3) CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1910.1000,1994 OSHA PEL (Construc):8H TWA 100 ppm (860 mg/m3) CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1926.55,1994 OSHA PEL (Shipyard):8H TWA 100 ppm (860 mg/m3) CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1915.1000,1993 OSHA PEL (Fed Cont):8H TWA 100 ppm (860 mg/m3) CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 41,50-204.50,1994 *** OCCUPATIONAL EXPOSURE LIMITS *** OEL-AUSTRALIA:TWA 100 ppm (860 mg/m3) JAN 1993 OEL-AUSTRIA:TWA 100 ppm (860 mg/m3) JAN 1993 OEL-BELGIUM:TWA 100 ppm (858 mg/m3) JAN 1993 OEL-DENMARK:TWA 100 ppm (860 mg/m3) JAN 1993 OEL-FINLAND:TWA 100 ppm (860 mg/m3);STEL 150 ppm (1290 mg/m3) JAN 1993 OEL-FRANCE:TWA 100 ppm (860 mg/m3) JAN 1993 OEL-GERMANY:TWA 100 ppm (860 mg/m3) JAN 1993 OEL-THE NETHERLANDS:TWA 100 ppm (860 mg/m3) JAN 1993 OEL-THE PHILIPPINES:TWA 100 ppm (860 mg/m3) JAN 1993 OEL-SWITZERLAND:TWA 100 ppm (860 mg/m3);STEL 200 ppm JAN 1993 OEL-TURKEY:TWA 100 ppm (860 mg/m3) JAN 1993 OEL-UNITED KINGDOM:TWA 100 ppm (860 mg/m3);STEL 150 ppm JAN 1993 OEL IN BULGARIA, COLOMBIA, JORDAN, KOREA check ACGIH TLV OEL IN NEW ZEALAND, SINGAPORE, VIETNAM check ACGIH TLV *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH RECOMMENDED EXPOSURE LEVEL (REL) : NIOSH REL TO DIFLUORODIBROMOMETHANE-air:10H TWA 100 ppm REFERENCE : NIOSH* National Institute for Occupational Safety and Health, U.S. Dept. of Health, Education, and Welfare, Reports and Memoranda. Volume(issue)/page/year: DHHS #92-100,1992 NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOHS - National Occupational Hazard Survey (1974) NOHS Hazard Code - 25515 No. of Facilities: 40 (estimated) No. of Industries: 2 No. of Occupations: 3 No. of Employees: 2234 (estimated) NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - 25515 No. of Facilities: 7 (estimated) No. of Industries: 1 No. of Occupations: 1 No. of Employees: 28 (estimated)

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H420

[ Personal Protective Equipment ]:
Gloves

[ Hazard Codes ]:
Xi:Irritant;

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
S37/39-S26-S59

[ RIDADR ]:
1941

[ RTECS ]:
PA7525000

[ Packaging Group ]:
III

[ Hazard Class ]:
9

Synthetic Route

Articles

Matrix isolation and computational study of isodifluorodibromomethane (F2CBr-Br): a route to Br2 formation in CF2Br2 photolysis.

J. Chem. Phys. 132(8) , 084503, (2010)

The photolysis products of dibromodifluoromethane (CF(2)Br(2)) were characterized by matrix isolation infrared and UV/Visible spectroscopy, supported by ab initio calculations. Photolysis at wavelengt...

S. Hayaski et al.

Chem. Lett. , 983, (1979)

J.S. Houlten et al.

Tetrahedron 49 , 8087, (1993)


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