2,2'-Bipyridyl 1,1'-Dioxide

Names

[ Name ]:
2,2'-Bipyridyl 1,1'-Dioxide

[Synonym ]:
2,2'-Bipyridine 1,1'-Dioxide 2,2'-Dipyridyl N,N'-Dioxide
MFCD00065169
2,2'-Bipyridyl-1,1'-dioxide
2,2'-Dipyridyl dioxide
2,2'-DIIODOBIPHENYL
2,2'-bipyridine-bis-1,1'-oxide
2,2'-Dipyridyl N,N'-dioxide2,2'-Bipyridine-1,1'-dioxide
2,2'-bipyridine-N,N'-dioxide

Chemical & Physical Properties

[ Density]:
1.2577 (rough estimate)

[ Boiling Point ]:
296-298ºC(lit.)

[ Melting Point ]:
296-298ºC(lit.)

[ Molecular Formula ]:
C₁₀H₈N₂O₂

[ Molecular Weight ]:
188.18300

[ Exact Mass ]:
188.05900

[ PSA ]:
50.92000

[ LogP ]:
2.21060

[ Index of Refraction ]:
1.5910 (estimate)

MSDS

Click to get detail MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :: DW1770000

CHEMICAL NAME :: 2,2'-Bipyridine, 1,1'-dioxide

CAS REGISTRY NUMBER :: 7275-43-6

LAST UPDATED :: 198612

DATA ITEMS CITED :: 1

MOLECULAR FORMULA :: C10-H8-N2-O2

MOLECULAR WEIGHT :: 188.20

WISWESSER LINE NOTATION :: T6NJ AO B- BT6NJ AO

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Intraperitoneal

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 2628 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: TOXIA6 Toxicon. (Pergamon Press Ltd., Headington Hill Hall, Oxford OX3 OBW, UK) V.1- 1962- Volume(issue)/page/year: 23,815,1985

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves

[ Hazard Codes ]:
Xi

[ Risk Phrases ]:
36/37/38

[ Safety Phrases ]:
26-36

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

[ RTECS ]:
DW1770000

[ HS Code ]:
2933399090

Synthetic Route

Click to get detail synthetic route

Customs

[ HS Code ]: 2933399090

[ Summary ]:
2933399090. other compounds containing an unfused pyridine ring (whether or not hydrogenated) in the structure. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%

Articles

Experimental electron density study of the supramolecular aggregation between 4,4'-dipyridyl-N,N'-dioxide and 1,4-diiodotetrafluorobenzene at 90 K.

Acta Crystallogr. B 60(Pt 5) , 559-68, (2004)

The electron density of the halogen-bonded complex of 4,4'-dipyridyl-N,N'-dioxide (bpNO) with 1,4-diiodotetrafluorobenzene (F(4)dIb) at 90 K has been determined by X-ray diffraction and analysed. The ...

Comparison of 2,2'-bipyridine and 2,2'-bipyridyl-N,N'-dioxide as ligands in zinc complexes.

Inorg. Chem. 49(19) , 8897-903, (2010)

The complexation abilities of 2,2'-bipyridine (bipy) and 2,2'-bipyridyl-N,N'-dioxide (bipydiox) toward zinc(II) and the influence of these ligands on the properties and reactivities of the investigate...

Spectroscopic study on the photophysical properties of lanthanide complexes with 2, 2'-bipyridine-N, N'-dioxide.

J. Fluoresc. 14(3) , 289-94, (2004)

Five novel lanthanide (Eu3+, Tb3+, Gd3+, Sm3+ and Dy3+) complexes with 2, 2'-bipyridine-N, N'-dioxide (bipyO2) were synthesized and characterized by elemental analysis, IR spectrum. The triplet state ...