3-Fluorobenzenesulfonyl chloride

Names

[ CAS No. ]:
701-27-9

[ Name ]:
3-Fluorobenzenesulfonyl chloride

[Synonym ]:
WSGR CF
MFCD00042286
m-Fluorobenzenesulfonyl chloride
3-Fluorobenzenesulfonyl chloride
Benzenesulfonyl chloride, 3-fluoro-
3-Fluorobenzenesulphonyl chloride

Chemical & Physical Properties

[ Density]:
1.5±0.1 g/cm3

[ Boiling Point ]:
245.4±13.0 °C at 760 mmHg

[ Melting Point ]:
7°C

[ Molecular Formula ]:
C₆H₄ClFO₂S

[ Molecular Weight ]:
194.611

[ Flash Point ]:
102.2±19.8 °C

[ Exact Mass ]:
193.960449

[ PSA ]:
42.52000

[ LogP ]:
2.41

[ Vapour Pressure ]:
0.0±0.5 mmHg at 25°C

[ Index of Refraction ]:
1.534

[ Storage condition ]:
2~8℃

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS05

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H314

[ Precautionary Statements ]:
P280-P305 + P351 + P338-P310

[ Personal Protective Equipment ]:
Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
C: Corrosive;

[ Risk Phrases ]:
R34

[ Safety Phrases ]:
S26-S36/37/39-S45-S8-S30-S23

[ RIDADR ]:
UN 3265 8/PG 2

[ WGK Germany ]:
3

[ Packaging Group ]:
II

[ Hazard Class ]:
8

[ HS Code ]:
2904909090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

DownStream

Customs

[ HS Code ]: 2904909090

[ Summary ]:
HS:2904909090 sulphonated, nitrated or nitrosated derivatives of hydrocarbons, whether or not halogenated VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:5.5% General tariff:30.0%

Articles

Palladium-Catalyzed Iterative C- H Bond Arylations: Synthesis of Medium-Size Heterocycles with a Bridgehead Nitrogen Atom. Hagui W, et al.

ChemCatChem 7(21) , 3544-3554, (2015)

Potassium fluoride catalyzed fluorodesulfonylations of aryl sulfonyl fluorides. Van der Puy M.

J. Org. Chem. 53(18) , 4398-4401, (1988)