1,1-Cyclopropanedicarboxylic acid dimethyl ester

Names

[ Name ]:
1,1-Cyclopropanedicarboxylic acid dimethyl ester

[Synonym ]:
cyclopropyl-1,1-dicarboxylic acid dimethyl ester
1,1-Bis(methoxycarbonyl)cyclopropane
CYCLOPROPANE DICARBOXYLATE
1,1-Cyclopropanedicarboxylic acid, dimethyl ester
L3TJ AVO1 AVO1
CDM
dimethyl cyclopropylmalonate
Dimethyl 1,1-cyclopropanedicarboxylate
DIMETHYL 1,1-CYCLOPROPANE-DICARBONYLATE
DIMETHYL 1,1-CYCLOPROPANE DIFORMATE
CYCLOPROPANE-1,1-DICARBOXYLIC ACID DIMETHYL ESTER
1,1-Cyclopropandicarbonsuredimethylester
EINECS 414-240-2
Dimethyl cyclopropane-1,1-dicarboxylate
MFCD00192079
cyclopropane-1,1-dicarboxylic acid diester

Chemical & Physical Properties

[ Density]:
1.2±0.1 g/cm3

[ Boiling Point ]:
157.6±13.0 °C at 760 mmHg

[ Molecular Formula ]:
C₇H₁₀O₄

[ Molecular Weight ]:
158.152

[ Flash Point ]:
67.2±18.2 °C

[ Exact Mass ]:
158.057907

[ PSA ]:
52.60000

[ LogP ]:
0.12

[ Vapour Pressure ]:
2.7±0.3 mmHg at 25°C

[ Index of Refraction ]:
1.474

[ Storage condition ]:
-20°C

MSDS

Click to get detail MSDS

Safety Information

[ Hazard Statements ]:
H412

[ Precautionary Statements ]:
P273

[ Personal Protective Equipment ]:
Eyeshields;Gloves;half-mask respirator (US);multi-purpose combination respirator cartridge (US)

[ Hazard Codes ]:
Xi

[ Risk Phrases ]:
R52/53

[ Safety Phrases ]:
S61

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
1

[ HS Code ]:
2917209090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

DownStream

Customs

[ HS Code ]: 2917209090

[ Summary ]:
2917209090 other cyclanic, cyclenic or cyclotherpenic polycarboxylic acids, their anhydrides, halides, peroxides, peroxyacids and their derivatives。supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward)。VAT:17.0%。tax rebate rate:9.0%。MFN tariff:6.5%。general tariff:30.0%

Articles

Asymmetric approach to the pentacyclic skeleton of Aspidosperma alkaloids via enantioselective intramolecular 1, 3-dipolar cycloaddition of carbonyl ylides catalyzed by chiral dirhodium (II) carboxylates. Nambu H, et al.

Tetrahedron Lett. 50(26) , 3675-78, (2009)