(+)-Trans-limonene1,2-epoxide
Names
[ CAS No. ]:
6909-30-4
[ Name ]:
(+)-Trans-limonene1,2-epoxide
[Synonym ]:
(1S,2R,4R)-4-Isopropenyl-1-methyl-1-cyclohexene 1,2-epoxide
D-LIMONENE 1,2-EPOXIDE
(1S,2R,4R)-limonene 1,2-oxide
(1S,4R)-1,2-Epoxy-p-menth-8-ene
(1R,4S)-trans-limonene oxide
(4R)-limonene 1alpha,2alpha-epoxide
(+)-trans-Limonene oxide
(1S,2R,4R)-limonene-1,2-epoxide
(+)-trans-p-Mentha-1,8-diene 1,2-epoxide
(+)-trans-Limonene 1,2-epoxide
(1S,2R,4R)-trans-1,2-limonene epoxide
(1S,2R)-1,2-epoxy-p-menth-8-ene
(1R,3R,6S)-6-methyl-3-prop-1-en-2-yl-7-oxabicyclo[4.1.0]heptane
2a2g
trans-d-Limonene oxide
limonene oxide
LEO
Chemical & Physical Properties
[ Density]:
0.930 g/mL at 20ºC(lit.)
[ Molecular Formula ]:
C10H16O
[ Molecular Weight ]:
152.23300
[ Flash Point ]:
65ºC
[ Exact Mass ]:
152.12000
[ PSA ]:
12.53000
[ LogP ]:
2.52010
[ Index of Refraction ]:
n20/D 1.466
[ Storage condition ]:
2-8°C
Safety Information
[ Personal Protective Equipment ]:
Eyeshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter
[ Hazard Codes ]:
F
[ RIDADR ]:
NONH for all modes of transport
[ WGK Germany ]:
3
[ HS Code ]:
2932999099
Precursor & DownStream
Precursor
DownStream
Customs
[ HS Code ]: 2932999099
[ Summary ]:
2932999099. other heterocyclic compounds with oxygen hetero-atom(s) only. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%
Articles
J. Am. Chem. Soc. 127(41) , 14339-47, (2005)
The catalytic mechanism of limonene epoxide hydrolase (LEH) was investigated theoretically using the density functional theory method B3LYP. LEH is part of a novel limonene degradation pathway found i...
QM/MM study of the mechanism of enzymatic limonene 1,2-epoxide hydrolysis.Biochim. Biophys. Acta 1824(2) , 263-8, (2012)
Limonene 1,2-epoxide hydrolase (LEH) is completely different from those of classic epoxide hydrolases (EHs) which catalyze the hydrolysis of epoxides to vicinal diols. A novel concerted general acid c...
Total synthesis of (+)-cymbodiacetal: a re-evaluation of the biomimetic route.J. Org. Chem. 75(24) , 8465-70, (2010)
A total synthesis of (+)-cymbodiacetal (1) has been completed from (R)-(+)-limonene oxide using a hetero-Diels-Alder cycloaddition as a key step. The key Diels-Alder cycloaddition proceeds with endo-s...