trimethylolpropane monoallyl ether

Names

[ CAS No. ]:
682-11-1

[ Name ]:
trimethylolpropane monoallyl ether

[Synonym ]:
EINECS 211-662-7
2-Allyloxymethyl-2-ethylpropanediol
2,2-bis(hydroxymethyl)-butyl allyl ether
2-(allyloxymethyl)-2-ethyl-1,3-propane diolbutanol
2-(Allyloxymethyl)-2-ethyl-1,3-propanediol
1-Butanol,2,2-(dihydroxymethyl)-,monoallyl ether
2-ethyl-2-[(prop-2-en-1-yloxy)methyl]propane-1,3-diol
1,1,1-Trimethylolpropane monoallyl ether
Trimethylolpropane monoallyl ether
MFCD00046753
Trimethylolpropane allyl ether

Chemical & Physical Properties

[ Density]:
1.01 g/mL at 25ºC(lit.)

[ Boiling Point ]:
160ºC33 mm Hg(lit.)

[ Melting Point ]:
-10ºC

[ Molecular Formula ]:
C₉H₁₈O₃

[ Molecular Weight ]:
174.23700

[ Flash Point ]:
>230 °F

[ Exact Mass ]:
174.12600

[ PSA ]:
49.69000

[ LogP ]:
0.57000

[ Index of Refraction ]:
n20/D 1.467(lit.)

MSDS

Click to get detail MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :: KM8800000

CHEMICAL NAME :: Ether, allyl (2,2-bis(hydroxymethyl)butyl)

CAS REGISTRY NUMBER :: 682-11-1

LAST UPDATED :: 199701

DATA ITEMS CITED :: 3

MOLECULAR FORMULA :: C9-H18-O3

MOLECULAR WEIGHT :: 174.27

WISWESSER LINE NOTATION :: Q1X2&1Q1O2U1

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 4930 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: IHFCAY Industrial Hygiene Foundation of America, Chemical and Toxicological Series, Bulletin. (Pittsburgh, PA) 1947-69. Volume(issue)/page/year: 6,1,1967 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOHS - National Occupational Hazard Survey (1974) NOHS Hazard Code - 84004 No. of Facilities: 5 (estimated) No. of Industries: 1 No. of Occupations: 2 No. of Employees: 49 (estimated)

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
Eyeshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
Xi

[ Risk Phrases ]:
36/37/38

[ Safety Phrases ]:
S26;S36

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
2

[ RTECS ]:
KM8800000

[ HS Code ]:
2909499000

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

DownStream

Customs

[ HS Code ]: 2909499000

[ Summary ]:
2909499000. ether-alcohols and their halogenated, sulphonated, nitrated or nitrosated derivatives. VAT:17.0%. Tax rebate rate:9.0%. . MFN tariff:5.5%. General tariff:30.0%