ethylbrom(difluor)acetat

[ Density]:
1.7±0.1 g/cm3

[ Boiling Point ]:
114.7±35.0 °C at 760 mmHg

[ Molecular Formula ]:
C₄H₅BrF₂O₂

[ Molecular Weight ]:
202.982

[ Flash Point ]:
23.2±25.9 °C

[ Exact Mass ]:
201.944092

[ PSA ]:
26.30000

[ LogP ]:
2.02

[ Vapour Pressure ]:
19.7±0.2 mmHg at 25°C

[ Index of Refraction ]:
1.412

[ Storage condition ]:
Flammables area

Click to get detail MSDS

[ Symbol ]:

GHS02, GHS05

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H225-H314

[ Precautionary Statements ]:
P210-P280-P305 + P351 + P338-P310

[ Personal Protective Equipment ]:
Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
C:Corrosive

[ Risk Phrases ]:
R10;R34

[ Safety Phrases ]:
S26-S36/37/39-S45-S16

[ RIDADR ]:
UN 2924 3/PG 2

[ WGK Germany ]:
3

[ Packaging Group ]:
II

[ Hazard Class ]:
3

[ HS Code ]:
2942000000

Precursor

DownStream

[ HS Code ]: 2915900090

[ Summary ]:
2915900090 other saturated acyclic monocarboxylic acids and their anhydrides, halides, peroxides and peroxyacids; their halogenated, sulphonated, nitrated or nitrosated derivatives VAT:17.0% Tax rebate rate:9.0% Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward) MFN tariff:5.5% General tariff:30.0%

Synthesis of 4-substituted 3,3-difluoropiperidines.

J. Org. Chem. 75(3) , 929-32, (2010)

Synthetic strategies toward 4-substituted 3,3-difluoropiperidines were evaluated. 4-Alkoxymethyl- and 4-aryloxymethyl-3,3-difluoropiperidines were synthesized via 1,4-addition of ethyl bromodifluoroac...

Visible-light-mediated fluoroalkylation of isocyanides with ethyl bromofluoroacetates: unified synthesis of mono- and difluoromethylated phenanthridine derivatives.

Org. Lett. 16(11) , 2938-41, (2014)

A practical and unified strategy has been described for the preparation of mono- and difluoromethylated phenanthridine derivatives using a visible-light-promoted alkylation and decarboxylation sequenc...

Enantioselective synthesis of α,α-difluoro-β-lactams using amino alcohol ligands.

Org. Biomol. Chem. 12(33) , 6484-9, (2014)

A practical and highly enantioselective Reformatsky reaction of ethyl bromodifluoroacetate with imines using a cheap and commercially available amino alcohol ligand is described. A variety of α,α-difl...

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