1-nitrobutane
Names
[ CAS No. ]:
627-05-4
[ Name ]:
1-nitrobutane
[Synonym ]:
n-butylnitrit
1-nitrobutane
4-nitro-1-butane
EINECS 210-980-3
MFCD00007409
nitrobutane
Chemical & Physical Properties
[ Density]:
0.973 g/mL at 25ºC(lit.)
[ Boiling Point ]:
152-153ºC(lit.)
[ Melting Point ]:
-81ºC(lit.)
[ Molecular Formula ]:
C4H9NO2
[ Molecular Weight ]:
103.12000
[ Flash Point ]:
44ºC
[ Exact Mass ]:
103.06300
[ PSA ]:
45.82000
[ LogP ]:
1.58640
[ Index of Refraction ]:
n20/D 1.410(lit.)
MSDS
Toxicological Information
CHEMICAL IDENTIFICATION
- RTECS NUMBER :
- EK5075000
- CHEMICAL NAME :
- Butane, 1-nitro-
- CAS REGISTRY NUMBER :
- 627-05-4
- BEILSTEIN REFERENCE NO. :
- 1743017
- LAST UPDATED :
- 199612
- DATA ITEMS CITED :
- 2
- MOLECULAR FORMULA :
- C4-H9-N-O2
- MOLECULAR WEIGHT :
- 103.14
- WISWESSER LINE NOTATION :
- WN4
HEALTH HAZARD DATA
ACUTE TOXICITY DATA
- TYPE OF TEST :
- LDLo - Lowest published lethal dose
- ROUTE OF EXPOSURE :
- Oral
- SPECIES OBSERVED :
- Rodent - rabbit
- DOSE/DURATION :
- 500 mg/kg
- TOXIC EFFECTS :
- Behavioral - somnolence (general depressed activity) Behavioral - ataxia Lungs, Thorax, or Respiration - respiratory stimulation
- REFERENCE :
- JIHTAB Journal of Industrial Hygiene and Toxicology. (Cambridge, MA) V.18-31, 1936-49. For publisher information, see AEHLAU. Volume(issue)/page/year: 22,315,1940 *** OCCUPATIONAL EXPOSURE LIMITS *** OEL-RUSSIA:STEL 30 mg/m3 JAN 1993
Safety Information
[ Symbol ]:
GHS02
[ Signal Word ]:
Warning
[ Hazard Statements ]:
H226
[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter
[ Risk Phrases ]:
R10
[ RIDADR ]:
UN 1993 3/PG 3
[ WGK Germany ]:
3
[ RTECS ]:
EK5075000
[ Packaging Group ]:
III
[ Hazard Class ]:
3.2
Synthetic Route
Precursor & DownStream
Precursor
DownStream
Articles
J. Chem. Phys. 136(6) , 064307, (2012)
We present low-energy velocity map photoelectron imaging results for bare and Ar-solvated 1-nitropropane and 1-nitrobutane anions. We report the adiabatic electron affinity of 1-nitropropane as (223 ±...
Hydrothermal reactions of 1-nitrobutane in high-temperature water. Iyer SD, et al.J. Supercrit. Fluids 9(1) , 26-32, (1996)