4-methylthioanisole
Names
[ CAS No. ]:
623-13-2
[ Name ]:
4-methylthioanisole
[Synonym ]:
p-Tolyl methyl sulfide
p-Methylphenyl methyl sulfide
1-Methyl-4-(methylsulfanyl)benzene
p-Cresyl methyl sulfide
EINECS 210-773-8
Benzene, 1-methyl-4- (methylthio)-
Methyl 4-methylphenyl sulfide
p-(Methylthio)toluene
Methyl p-cresyl sulfide
Benzene, 1-methyl-4-(methylthio)-
4-Methyl-(1-thiaethyl)benzene
1-methyl-4-methylsulfanylbenzene
MFCD00008560
Sulfide, methyl p-tolyl (8CI)
Sulfide, methyl p-tolyl
4-methylthioanisole
Chemical & Physical Properties
[ Density]:
1.0±0.1 g/cm3
[ Boiling Point ]:
222.7±0.0 °C at 760 mmHg
[ Molecular Formula ]:
C8H10S
[ Molecular Weight ]:
138.230
[ Flash Point ]:
85.0±0.0 °C
[ Exact Mass ]:
138.050323
[ PSA ]:
25.30000
[ LogP ]:
3.16
[ Vapour Pressure ]:
0.1±0.4 mmHg at 25°C
[ Index of Refraction ]:
1.559
MSDS
Safety Information
[ Symbol ]:
GHS07
[ Signal Word ]:
Warning
[ Hazard Statements ]:
H302
[ Personal Protective Equipment ]:
Eyeshields;Gloves;half-mask respirator (US);multi-purpose combination respirator cartridge (US)
[ Hazard Codes ]:
Xn
[ Risk Phrases ]:
22
[ Safety Phrases ]:
S24/25
[ RIDADR ]:
3334
[ WGK Germany ]:
3
[ Hazard Class ]:
9
[ HS Code ]:
2930909090
Synthetic Route
Customs
[ HS Code ]: 2930909090
[ Summary ]:
2930909090. other organo-sulphur compounds. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:30.0%
Articles
J. Am. Chem. Soc. 125(2) , 308-9, (2003)
fac-[RuII(Cl)(dpp)(L3)]+ (L3 = tris(pyrid-2-yl)methoxymethane (tpmm) = [1A]+ and tris(pyrid-2-yl)pentoxymethane (tppm) = [1B]+ and dpp = di(pyrazol-1-yl)propane) rapidly undergo ligand substitution wi...
Chloroperoxidase and hydrogen peroxide: An efficient system for enzymatic enantioselective sulfoxidations Colonna S, et al.Tetrahedron Asymmetry 3(1) , 95-106, (1992)