tert-butyl methyl sulfide

Names

[ Name ]:
tert-butyl methyl sulfide

[Synonym ]:
t-butyl methyl sulfide
2-thiabutane,3,3-dimethyl
Methyl t-butyl sulfide
(CH3)3CSCH3
3,3-Dimethyl-2-thiabutane
TERT-BUTYL METHYL SULPHIDE
tert-butyl methyl thioether
sulfure de tert-butyle et de methyle
tert-butylmethylsulfide
METHYL TERT-BUTYL SULFIDE
MFCD00008840
Sulfide,tert-butyl methyl

Chemical & Physical Properties

[ Density]:
0.826

[ Boiling Point ]:
101-102ºC(lit.)

[ Melting Point ]:
-82.31°C

[ Molecular Formula ]:
C₅H₁₂S

[ Molecular Weight ]:
104.21400

[ Flash Point ]:
25 °F

[ Exact Mass ]:
104.06600

[ PSA ]:
25.30000

[ LogP ]:
2.14790

[ Appearance of Characters ]:
liquid

[ Index of Refraction ]:
n20/D 1.44(lit.)

[ Storage condition ]:
Flammables area

[ Water Solubility ]:
Difficult to mix.

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS02, GHS07

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H225-H315-H319-H335

[ Precautionary Statements ]:
P210-P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
F,Xi

[ Risk Phrases ]:
11-36/37/38

[ Safety Phrases ]:
16-26-36/37/39

[ RIDADR ]:
UN 1993 3/PG 2

[ WGK Germany ]:
3

[ Packaging Group ]:
II

[ HS Code ]:
2930909090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

DownStream

Customs

[ HS Code ]: 2930909090

[ Summary ]:
2930909090. other organo-sulphur compounds. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:30.0%

Articles

Alloxazine-cyclodextrin conjugates for organocatalytic enantioselective sulfoxidations.

Org. Biomol. Chem. 9(21) , 7318-26, (2011)

Four structurally different alloxazine-cyclodextrin conjugates were prepared and tested as catalysts for the enantioselective oxidation of prochiral sulfides to sulfoxides by hydrogen peroxide in aque...