Ethyl methylmalonate

Names

[ CAS No. ]:
609-08-5

[ Name ]:
Ethyl methylmalonate

[Synonym ]:
Ethyl methylmalonate
Propanedioic acid, 2-methyl-, diethyl ester
Propanedioic acid, methyl-, diethyl ester
MFCD00009162
Ethyl methylmalonate (VAN)
diethyl 2-methylpropanedioate
diethyl 2-methylmalonate
EINECS 210-175-7
Diethyl methylmalonate
Diethyl ethanedicarboxylate
Malonic acid, methyl-, diethyl ester (8CI)
Malonic acid, methyl-, diethyl ester
Diethylmethylmalonate

Chemical & Physical Properties

[ Density]:
1.0±0.1 g/cm3

[ Boiling Point ]:
204.4±8.0 °C at 760 mmHg

[ Molecular Formula ]:
C₈H₁₄O₄

[ Molecular Weight ]:
174.194

[ Flash Point ]:
76.7±0.0 °C

[ Exact Mass ]:
174.089203

[ PSA ]:
52.60000

[ LogP ]:
1.05

[ Vapour Pressure ]:
0.3±0.4 mmHg at 25°C

[ Index of Refraction ]:
1.421

[ Water Solubility ]:
immiscible

MSDS

Click to get detail MSDS

Safety Information

[ Personal Protective Equipment ]:
Eyeshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
Xi

[ Safety Phrases ]:
S23-S24/25

[ WGK Germany ]:
3

[ HS Code ]:
2917190090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

DownStream

Customs

[ HS Code ]: 2917190090

[ Summary ]:
2917190090 acyclic polycarboxylic acids, their anhydrides, halides, peroxides, peroxyacids and their derivatives VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:30.0%

Articles

An erythromycin process improvement using the diethyl methylmalonate-responsive (Dmr) phenotype of the Saccharopolyspora erythraea mutB strain.

Appl. Microbiol. Biotechnol. 93(4) , 1575-83, (2012)

The Saccharopolyspora erythraea mutB knockout strain, FL2281, having a block in the methylmalonyl-CoA mutase reaction, was found to carry a diethyl methylmalonate-responsive (Dmr) phenotype in an oil-...

Abnormal Michael reaction. Reaction between 2-cyclohexenone and diethyl methylmalonate. Risinger GE and Haag WG.

J. Org. Chem. 38(20) , 3546-3647, (1973)

Alkylation reaction of poly (chloromethylstyrene) with malononitrile and diethyl methylmalonate using phase transfer catalysts. Nishikubo T, et al.

Makromol. Chem. 2(6-7) , 387-392, (1981)