3,3-Dimethoxy-1-propene
Names
[ CAS No. ]:
6044-68-4
[ Name ]:
3,3-Dimethoxy-1-propene
[Synonym ]:
1-Propene, 3,3-dimethoxy-
3,3-Dimethoxy-1-propene
EINECS 227-936-4
3,3-Dimethoxyprop-1-ene
MFCD00008632
AcroleinDimethylAcetal
Chemical & Physical Properties
[ Density]:
0.9±0.1 g/cm3
[ Boiling Point ]:
89.5±0.0 °C at 760 mmHg
[ Molecular Formula ]:
C5H10O2
[ Molecular Weight ]:
102.132
[ Flash Point ]:
-2.8±0.0 °C
[ Exact Mass ]:
102.068077
[ PSA ]:
18.46000
[ LogP ]:
0.65
[ Vapour Pressure ]:
66.0±0.1 mmHg at 25°C
[ Index of Refraction ]:
1.392
[ Storage condition ]:
2-8°C
MSDS
Toxicological Information
CHEMICAL IDENTIFICATION
- RTECS NUMBER :
- UC8500000
- CHEMICAL NAME :
- 1-Propene, 3,3-dimethoxy-
- CAS REGISTRY NUMBER :
- 6044-68-4
- BEILSTEIN REFERENCE NO. :
- 1700037
- LAST UPDATED :
- 199612
- DATA ITEMS CITED :
- 1
- MOLECULAR FORMULA :
- C5-H10-O2
- MOLECULAR WEIGHT :
- 102.15
- WISWESSER LINE NOTATION :
- 1OYO1&1U1
HEALTH HAZARD DATA
ACUTE TOXICITY DATA
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Intravenous
- SPECIES OBSERVED :
- Rodent - mouse
- DOSE/DURATION :
- 56 mg/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- REFERENCE :
- CSLNX* U.S. Army Armament Research & Development Command, Chemical Systems Laboratory, NIOSH Exchange Chemicals. (Aberdeen Proving Ground, MD 21010) Volume(issue)/page/year: NX#03553
Safety Information
[ Symbol ]:
GHS02
[ Signal Word ]:
Danger
[ Hazard Statements ]:
H225
[ Precautionary Statements ]:
P210
[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter
[ Hazard Codes ]:
F:Flammable;
[ Risk Phrases ]:
R11
[ Safety Phrases ]:
S16-S23-S24/25-S29-S33
[ RIDADR ]:
UN 3384 6.1/PG 1
[ WGK Germany ]:
3
[ RTECS ]:
UC8500000
[ Packaging Group ]:
II
[ Hazard Class ]:
3.1
[ HS Code ]:
2911000000
Synthetic Route
Precursor & DownStream
Precursor
DownStream
Customs
[ HS Code ]: 2911000000
[ Summary ]:
2911000000 acetals and hemiacetals, whether or not with other oxygen function, and their halogenated, sulphonated, nitrated or nitrosated derivatives。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。MFN tariff:5.5%。General tariff:30.0%
Articles
J. Am. Chem. Soc. 126(39) , 12246-7, (2004)
Acrolein dimethyl acetal (ADMA) can be copolymerized with ethene using a cationic alpha-diimine palladium chelate catalyst to yield branched copolymers. Catalyst deactivation occurs via methanol elimi...
An expeditious synthesis of 4-hydroxy-2E-nonenal (4-HNE), its dimethyl acetal and of related compounds.Chem. Phys. Lipids 150(2) , 239-43, (2007)
The facile one step synthesis of 4-hydroxy-2E-nonenal and its dimethyl acetal via a cross-metathesis reaction between commercially available octen-3-ol and acrolein or its dimethyl acetal is reported....