methyl 4-bromocrotonate

Names

[ Name ]:
methyl 4-bromocrotonate

[Synonym ]:
Methyl (E)-4-bromo-2-butenoate
EINECS 214-251-0
methyl trans-4-bromo-2-butenoate
Methyl trans-4-bromocrotonate
Methyl (2E)-4-bromobut-2-enoate
(E)-4-Bromo-crotonic acid methyl ester
(E)-Methyl 4-bromocrotonate
methyl 4-bromo-crotonate
trans-Methyl-4-bromocrotonate
MFCD00000246
(E)-4-Bromo-but-2-enoicacidmethylester
4-BROMOCROTONIC ACID METHYL ESTER

Chemical & Physical Properties

[ Density]:
1.522 g/mL at 25ºC(lit.)

[ Boiling Point ]:
83-85ºC13 mm Hg(lit.)

[ Melting Point ]:
83-85ºC

[ Molecular Formula ]:
C₅H₇BrO₂

[ Molecular Weight ]:
179.01200

[ Flash Point ]:
197 °F

[ Exact Mass ]:
177.96300

[ PSA ]:
26.30000

[ LogP ]:
1.11050

[ Index of Refraction ]:
n20/D 1.501

[ Storage condition ]:
2-8°C

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
Eyeshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
Xi

[ Risk Phrases ]:
37/38-41

[ Safety Phrases ]:
26-39

[ WGK Germany ]:
3

[ RTECS ]:
GQ3120000

Articles

Incorporation of 3H from delta-(L-alpha-amino (4,5-3H)adipyl)-L-cysteinyl-D-(4,4-3H)valine into isopenicillin N.

Biochem. J. 184(2) , 421-6, (1979)

1. delta-(L-alpha-Amino[4,5-3H]adipyl)-L-cysteinyl-D-[4,4-3H]valine has been synthesized from its constituent amino acids, the L-alpha-amino[4,5-3H]adipic acid being obtained by reduction with 3H2 of ...

An Allylpalladium (IV) Intermediate in the Synthesis of Highly Substituted Benzoxepines and Benzopyrans via Reactions of Stable Pallada (II) cycles with Allyl Bromides. Guo R, et al.

Organometallics 26(15) , 3784-83, (2007)