Oxo[tris(2-propanolato)]vanadium

Names

[ Name ]:
Oxo[tris(2-propanolato)]vanadium

[Synonym ]:
Oxo[tris(propan-2-olato)]vanadium
Vanadium, oxotris(2-propanolato)-
Oxo-tri-i-propoxyvanadium
Oxo[tris(2-propanolato)]vanadium
Vanadyl isopropoxide
MFCD00015017
Vanadyl isopropylate
Oxotriisopropoxyvanadium
Vanadiumisopropoxideoxide
isopropyl orthovanadate
vanadium triisopropoxide oxide
Vanadyl triisopropoxide
vanadium isopropoxide
Triisopropylorthovanadate
EINECS 226-997-4

Chemical & Physical Properties

[ Density]:
1.035 g/mL at 25 °C(lit.)

[ Boiling Point ]:
80-82 °C2 mm Hg(lit.)

[ Melting Point ]:
-11°C

[ Molecular Formula ]:
C₉H₂₁O₄V

[ Molecular Weight ]:
244.202

[ Flash Point ]:
113 °F

[ Exact Mass ]:
244.087952

[ PSA ]:
44.76000

[ LogP ]:
2.50830

[ Index of Refraction ]:
n20/D 1.479(lit.)

[ Storage condition ]:
Flammables area

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS02, GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H226-H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
Xi:Irritant;

[ Risk Phrases ]:
R10;R36/37/38

[ Safety Phrases ]:
S16-S26-S27

[ RIDADR ]:
UN 1993 3/PG 3

[ WGK Germany ]:
3

[ Packaging Group ]:
III

[ Hazard Class ]:
3

Synthetic Route

Click to get detail synthetic route

Articles

Solution processable broadband transparent mixed metal oxide nanofilm optical coatings via substrate diffusion doping.

Nanoscale 7 , 20227-37, (2015)

Devices composed of transparent materials, particularly those utilizing metal oxides, are of significant interest due to increased demand from industry for higher fidelity transparent thin film transi...

Stepwise Cluster Assembly Using VO(2)(acac) as a Precursor: cis-[VO(OCH(CH(3))(2))(acac)(2)], [V(2)O(2)(&mgr;-OCH(3))(2)(acac)(2)(OCH(3))(2)], [V(3)O(3){&mgr;,&mgr;-(OCH(2))(3)CCH(3)}(2)(acac)(2)(OC(2)H(5))], and [V(4)O(4)(&mgr;-O)(2)(&mgr;-OCH(3))(2)(&mgr;(3)-OCH(3))(2)(acac)(2)(OCH(3))(2)].2CH(3)CN(1).

Inorg. Chem. 37 , 5439, (1998)

The studies of an underexplored synthetic reagent, VO(2)(acac) (Hacac = acetylacetone) and semirational strategies for the formation of a complete series of simple vanadium(V) alkoxide clusters in alc...