2-chloropropene

Names

[ CAS No. ]:
557-98-2

[ Name ]:
2-chloropropene

[Synonym ]:
2-chloroprop-1-ene
MFCD00000859
EINECS 209-187-5

Chemical & Physical Properties

[ Density]:
0.9±0.1 g/cm3

[ Boiling Point ]:
22.6±0.0 °C at 760 mmHg

[ Melting Point ]:
-138 °C

[ Molecular Formula ]:
C₃H₅Cl

[ Molecular Weight ]:
76.525

[ Flash Point ]:
-33.9±14.1 °C

[ Exact Mass ]:
76.007980

[ LogP ]:
1.99

[ Vapour Pressure ]:
827.6±0.0 mmHg at 25°C

[ Index of Refraction ]:
1.398

MSDS

Click to get detail MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :: UC7200000

CHEMICAL NAME :: Propene, 2-chloro-

CAS REGISTRY NUMBER :: 557-98-2

BEILSTEIN REFERENCE NO. :: 1361376

LAST UPDATED :: 199710

DATA ITEMS CITED :: 7

MOLECULAR FORMULA :: C3-H5-Cl

MOLECULAR WEIGHT :: 76.53

WISWESSER LINE NOTATION :: GY1&U1

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: LC50 - Lethal concentration, 50 percent kill

ROUTE OF EXPOSURE :: Inhalation

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 267 gm/m3

TOXIC EFFECTS :: Behavioral - general anesthetic Lungs, Thorax, or Respiration - respiratory depression Lungs, Thorax, or Respiration - other changes

TYPE OF TEST :: TCLo - Lowest published toxic concentration

ROUTE OF EXPOSURE :: Inhalation

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 191 gm/m3/30M/1W-I

TOXIC EFFECTS :: Lungs, Thorax, or Respiration - other changes Blood - hemorrhage

MUTATION DATA

TYPE OF TEST :: Mutation in microorganisms

TEST SYSTEM :: Bacteria - Salmonella typhimurium

DOSE/DURATION :: 100 umol/plate

REFERENCE :: BCPCA6 Biochemical Pharmacology. (Pergamon Press Inc., Maxwell House, Fairview Park, Elmsford, NY 10523) V.1- 1958- Volume(issue)/page/year: 29,2611,1980 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - X5380 No. of Facilities: 3 (estimated) No. of Industries: 1 No. of Occupations: 6 No. of Employees: 132 (estimated) No. of Female Employees: 3 (estimated)

Safety Information

[ Symbol ]:

GHS02, GHS07

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H224-H319-H335

[ Precautionary Statements ]:
P210-P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US)

[ Hazard Codes ]:
F+,Xi

[ Risk Phrases ]:
12-36/37

[ Safety Phrases ]:
S16-S26-S36

[ RIDADR ]:
UN 2456 3/PG 1

[ WGK Germany ]:
3

[ RTECS ]:
UC7200000

[ Packaging Group ]:
I

[ Hazard Class ]:
3

Synthetic Route

Click to get detail synthetic route

Articles

Quantum chemical and kinetics study of the thermal gas phase decomposition of 2-chloropropene.

J. Phys. Chem. A 117(40) , 10218-27, (2013)

A detailed theoretical study of the kinetics of the thermal decomposition of 2-chloropropene over the 600-1400 K temperature range has been done. The reaction takes place through the elimination of HC...

One-photon mass-analyzed threshold ionization spectroscopy of 2-chloropropene (2-C3H5Cl) and its vibrational assignment based on the density-functional theory calculations.

J. Chem. Phys. 123(4) , 044306, (2005)

A high-quality mass-analyzed threshold ionization (MATI) spectrum of 2-chloropropene, 2-C3H5Cl, is reported. Its ionization energy determined for the first time from the 0-0 band position was 9.5395+/...

Determination of absolute photoionization cross sections for isomers of C₃H₅: allyl and 2-propenyl radicals. Robinson JC, et al.

Chem. Phys. Lett. 383(5) , 601-5, (2004)