9-Bromo-9-phenylfluorene
Names
[ CAS No. ]:
55135-66-5
[ Name ]:
9-Bromo-9-phenylfluorene
[Synonym ]:
9H-Fluorene, 9-bromo-9-phenyl-
9-bromanyl-9-phenyl-fluorene
9-phenyl-9-fluorenyl bromide
9-Bromo-9-phenyl-9H-fluorene
9-brom-9-phenyl-9h-fluoren
MFCD00075522
9-phenyl-9-bromofluorene
9-phenyl-9H-fluoren-9-yl bromide
Chemical & Physical Properties
[ Density]:
1.4±0.1 g/cm3
[ Boiling Point ]:
394.3±41.0 °C at 760 mmHg
[ Melting Point ]:
99-101 °C(lit.)
[ Molecular Formula ]:
C19H13Br
[ Molecular Weight ]:
321.211
[ Flash Point ]:
172.5±17.3 °C
[ Exact Mass ]:
320.020050
[ LogP ]:
5.57
[ Vapour Pressure ]:
0.0±0.9 mmHg at 25°C
[ Index of Refraction ]:
1.688
MSDS
Safety Information
[ Symbol ]:
GHS05
[ Signal Word ]:
Danger
[ Hazard Statements ]:
H314
[ Precautionary Statements ]:
P280-P305 + P351 + P338-P310
[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face particle respirator type N100 (US);Gloves;respirator cartridge type N100 (US);type P1 (EN143) respirator filter;type P3 (EN 143) respirator cartridges
[ Hazard Codes ]:
C:Corrosive;
[ Risk Phrases ]:
R34
[ Safety Phrases ]:
S26-S27-S28-S36/37/39-S45
[ RIDADR ]:
UN 3261 8/PG 2
[ WGK Germany ]:
3
[ Packaging Group ]:
II
[ Hazard Class ]:
8
[ HS Code ]:
2903999090
Synthetic Route
Precursor & DownStream
Precursor
DownStream
Customs
[ HS Code ]: 2903999090
[ Summary ]:
2903999090 halogenated derivatives of aromatic hydrocarbons VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:5.5% General tariff:30.0%
Articles
J. Am. Chem. Soc. 109(1) , 236-9, (1987)
Surrogates for Chiral Aminomalondialdehyde. Synthesis of N-(9-Phenylfluoren-9-yl) serinal and N-(9-Phenylfluoren-9-yl) vinylglycinal. Lubell WD and Rapoport H.
J. Org. Chem. 54(16) , 3824-31, (1989)
Synthesis of 5-substituted 1-hydroxypyrazoles through directed lithiation of 1-(benzyloxy) pyrazole. Vedso P and Begtrup M.
J. Org. Chem. 60(16) , 4995-98, (1995)