Benzyl bromoacetate

Names

[ Name ]:
Benzyl bromoacetate

[Synonym ]:
benzyl 2-bromo-acetate
Bromoacetic acid benzyl ester
phenylmethyl 2-bromoacetate
Merbac 35
EINECS 226-611-4
Acetic acid,bromo-,benzyl ester
phenylmethyl bromoacetate
Benzyl bromoacetate
Acetic acid,bromo-,phenylmethyl ester
2-Bromoacetic Acid Phenylmethyl Ester
MFCD00000190
Acetic acid, 2-bromo-, phenylmethyl ester
Caswell No. 082A
bromoacetic acid. phenylmethyl ester

Chemical & Physical Properties

[ Density]:
1.5±0.1 g/cm3

[ Boiling Point ]:
287.8±0.0 °C at 760 mmHg

[ Molecular Formula ]:
C₉H₉BrO₂

[ Molecular Weight ]:
229.071

[ Flash Point ]:
116.5±20.4 °C

[ Exact Mass ]:
227.978592

[ PSA ]:
26.30000

[ LogP ]:
2.66

[ Vapour Pressure ]:
0.0±0.6 mmHg at 25°C

[ Index of Refraction ]:
1.556

MSDS

Click to get detail MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :: AF5957215

CHEMICAL NAME :: Acetic acid, bromo-, benzyl ester

CAS REGISTRY NUMBER :: 5437-45-6

BEILSTEIN REFERENCE NO. :: 0973658

LAST UPDATED :: 199712

DATA ITEMS CITED :: 1

MOLECULAR FORMULA :: C9-H9-Br-O2

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
Eyeshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
Xi:Irritant;

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
S26-S37/39

[ RIDADR ]:
2810

[ WGK Germany ]:
3

[ RTECS ]:
AF5957215

[ Hazard Class ]:
6.1

[ HS Code ]:
29159080

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

DownStream

Customs

[ HS Code ]: 2915900090

[ Summary ]:
2915900090 other saturated acyclic monocarboxylic acids and their anhydrides, halides, peroxides and peroxyacids; their halogenated, sulphonated, nitrated or nitrosated derivatives VAT:17.0% Tax rebate rate:9.0% Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward) MFN tariff:5.5% General tariff:30.0%

Articles

Synthesis of VIP-lipopeptide using a new linker to modify liposomes: towards the development of a drug delivery system for active targeting.

Chem. Pharm. Bull. 61(11) , 1184-7, (2013)

A new component for the solid phase peptide synthesis of lipopeptide, 2-[(4R,5R)-5-({[(9H-fluoren-9-yl)methoxy]carbonylaminomethyl}-2,2-dimethyl-1,3-dioxolan-4-yl)methoxy]acetic acid (2), was designed...