tris(methylthio)methane
Names
[ CAS No. ]:
5418-86-0
[ Name ]:
tris(methylthio)methane
[Synonym ]:
Methyl orthotrithioformate
Trithiomethoxymethane
Trimethyl trithioorthoformate
Orthoformic acid,trithio-,trimethyl ester
MFCD00009851
Chemical & Physical Properties
[ Density]:
1.16 g/mL at 25ºC(lit.)
[ Boiling Point ]:
102ºC15 mm Hg(lit.)
[ Melting Point ]:
16ºC(lit.)
[ Molecular Formula ]:
C4H10S3
[ Molecular Weight ]:
154.31700
[ Flash Point ]:
204 °F
[ Exact Mass ]:
153.99400
[ PSA ]:
75.90000
[ LogP ]:
2.35900
[ Index of Refraction ]:
n20/D 1.577(lit.)
MSDS
Safety Information
[ Symbol ]:
GHS07
[ Signal Word ]:
Warning
[ Hazard Statements ]:
H315-H319-H335
[ Precautionary Statements ]:
P261-P305 + P351 + P338
[ Personal Protective Equipment ]:
Eyeshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter
[ Hazard Codes ]:
Xi: Irritant;
[ Risk Phrases ]:
R36/37/38
[ Safety Phrases ]:
26-36
[ RIDADR ]:
UN 2810 6
[ WGK Germany ]:
3
[ HS Code ]:
2930909090
Synthetic Route
Customs
[ HS Code ]: 2930909090
[ Summary ]:
2930909090. other organo-sulphur compounds. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:30.0%
Articles
Org. Lett. 13(5) , 948-51, (2011)
An efficient catalytic asymmetric synthesis of chiral γ-butenolides was developed based on the hetero-allylic asymmetric alkylation (h-AAA) in combination with ring closing metathesis (RCM). The synth...
Research on L-nucleosides. Synthesis and biological evaluation of a series of L- and D-2',3'-dideoxy-3'-[tris(methylthio)methyl]-beta-pentofuranosyl nucleosides.Bioorg. Med. Chem. 11(3) , 357-66, (2003)
Novel nucleoside analogues of both D and L enantiomeric series were prepared by coupling reaction between a 2',3'-dideoxy-3'-modified furanose moiety and four different nucleobases. Though in all case...
From ketones, aldehydes or alkyl halides to terminal 1, 1-difluoroolefins using BrF3. Hagooly A and Rozen S.J. Fluor. Chem. 126(8) , 1239-45, (2005)