Ethyl benzimidate hydrochloride

Names

[ Name ]:
Ethyl benzimidate hydrochloride

[Synonym ]:
MFCD00043246
Benzenecarboximidic acid, ethyl ester
Ethyl benzenecarboximidate
Ethyl benzimidate
Phenylethoxymethylenamine
EINECS 226-248-1
ethyl benzenecarboximidate,hydrochloride
Iminobenzyl ethyl ether

Chemical & Physical Properties

[ Density]:
1.0±0.1 g/cm3

[ Boiling Point ]:
192.9±23.0 °C at 760 mmHg

[ Melting Point ]:
125ºC (dec.)

[ Molecular Formula ]:
C₉H₁₂ClNO

[ Molecular Weight ]:
149.190

[ Flash Point ]:
70.5±22.6 °C

[ Exact Mass ]:
149.084061

[ PSA ]:
33.08000

[ LogP ]:
1.95

[ Vapour Pressure ]:
0.7±0.4 mmHg at 25°C

[ Index of Refraction ]:
1.502

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves

[ Hazard Codes ]:
Xi:Irritant;

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
S26

[ RIDADR ]:
NONH for all modes of transport

[ HS Code ]:
2925290090

Synthetic Route

Click to get detail synthetic route

Customs

[ HS Code ]: 2925290090

[ Summary ]:
2925290090 other imines and their derivatives; salts thereof。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。MFN tariff:6.5%。General tariff:30.0%

Articles

Efficient asymmetric synthesis of (S)- and (R)-N-Fmoc-S-trityl-alpha-methylcysteine using camphorsultam as a chiral auxiliary.

J. Org. Chem. 69(13) , 4551-4, (2004)

(1R)-(+)-2,10- and (1S)-(-)-2,10-camphorsultam were acylated with ethyl 2-phenylthiazoline 4-carboxylate to afford (+)- and (-)-2-phenylthiazolinylcamphorsultam, which were stereoselectively alkylated...

The Synthesis of Substituted Penicillins and Simpler Structural Analogs. III. Phthalimido ß-Lactam-Thiazolidines Derived from Penicillamine. Sheehan JC, et al.

J. Am. Chem. Soc. 73(9) , 4373-4375, (1951)