L-(+)-Erythrulose
Names
[ CAS No. ]:
533-50-6
[ Name ]:
L-(+)-Erythrulose
[Synonym ]:
L-Glycero-2-tetrulose
L-glyceraldehyde-3-phosphate
glyceraldehyde 3-phosphate dianion
calcium L-glycerate dihydrate
L-glyceric acid hemicalcium salt
L-erythulose
L-(+)-Erythrulose
(3S)-1,3,4-Trihydroxy-2-butanone
Q1YQV1Q &&L or S Form
S-1,3,4-Trihydroxy-2-butanone
Erythrulose
(S)-1,3,4-Trihydroxy-2-butanone
GLYCERALDEHYDE 3-PHOSPHATE
(3S)-1,3,4-Trihydroxybutan-2-one
L-Erythrulose
D-Gylcerinaldehyd-3-phosphat
Calcium-L-glycerat
2-Butanone, 1,3,4-trihydroxy-, (3S)-
D-glyceric acid hemicalcium salt
2-hydroxy-3-oxopropyl phosphate
Chemical & Physical Properties
[ Density]:
1.4±0.1 g/cm3
[ Boiling Point ]:
349.6±27.0 °C at 760 mmHg
[ Molecular Formula ]:
C4H8O4
[ Molecular Weight ]:
120.104
[ Flash Point ]:
179.4±20.2 °C
[ Exact Mass ]:
120.042259
[ PSA ]:
77.76000
[ LogP ]:
-0.98
[ Vapour Pressure ]:
0.0±1.7 mmHg at 25°C
[ Index of Refraction ]:
1.507
MSDS
Safety Information
[ Personal Protective Equipment ]:
Eyeshields;Gloves
[ RIDADR ]:
NONH for all modes of transport
[ HS Code ]:
2914400090
Synthetic Route
Precursor & DownStream
Precursor
DownStream
Customs
[ HS Code ]: 2914400090
[ Summary ]:
2914400090 other ketone-alcohols and ketone-aldehydes。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。MFN tariff:5.5%。General tariff:30.0%
Articles
J. Org. Chem. 68 , 8577-8582, (2003)
Both matched and mismatched diastereoselections have been observed in aldol reactions of the B,B-dicyclohexylboron enolate of a protected l-erythrulose derivative with a range of chiral aldehydes. The...
Aldol reactions between L-erythrulose derivatives and chiral alpha-amino and alpha-fluoro aldehydes: competition between Felkin-Anh and Cornforth transition states.Chemistry 14 , 9240-9254, (2008)
Both matched and mismatched diastereoselection have been observed in aldol reactions of a boron enolate of a protected L-erythrulose derivative with several chiral alpha-fluoro and alpha-amino aldehyd...
Double diastereoselection in aldol reactions mediated by dicyclohexylchloroborane between chiral aldehydes and a chiral ethyl ketone derived from L-erythrulose. synthesis of a C1-C9 fragment of the structure of the antifungal metabolite soraphen A1alpha.J. Org. Chem. 70 , 8130-8139, (2005)
[Chemical reaction: See text] Both matched and mismatched diastereoselections have been observed in the aldol reactions of a range of chiral aldehydes with the dicyclohexylboron enolate of a chiral et...