a-Oxobenzeneacetaldehyde Aldoxime
Names
[ CAS No. ]:
532-54-7
[ Name ]:
a-Oxobenzeneacetaldehyde Aldoxime
[Synonym ]:
(2E)-2-(Hydroxyimino)-1-phenylethanone
Benzeneacetaldehyde, α-oxo-, aldoxime
EINECS 208-539-5
2-Oxo-2-phenylacetaldehyde oxime
2-Hydroxyiminoacetophenone
ω-(Hydroxyimino)acetophenone
Isonitrosoacetophenone
(2E)-2-hydroxyimino-1-phenylethanone
Phenylglyoxaldoxim
a-Oxobenzeneacetaldehyde Aldoxime
Benzoylformaldoxime
ω-Isonitrosoacetophenone
Benzeneacetaldehyde, α-oxo-, α-oxime
MFCD00002122
Chemical & Physical Properties
[ Density]:
1.1±0.1 g/cm3
[ Boiling Point ]:
305.7±25.0 °C at 760 mmHg
[ Melting Point ]:
123-125 °C
[ Molecular Formula ]:
C8H7NO2
[ Molecular Weight ]:
149.147
[ Flash Point ]:
138.7±23.2 °C
[ Exact Mass ]:
149.047684
[ PSA ]:
49.66000
[ LogP ]:
1.41
[ Vapour Pressure ]:
0.0±0.7 mmHg at 25°C
[ Index of Refraction ]:
1.543
[ Storage condition ]:
2-8°C
[ Water Solubility ]:
SOLUBLE IN COLD WATER
MSDS
Toxicological Information
CHEMICAL IDENTIFICATION
- RTECS NUMBER :
- MD3325000
- CHEMICAL NAME :
- Glyoxal, 1-phenyl-, 2-oxime
- CAS REGISTRY NUMBER :
- 532-54-7
- BEILSTEIN REFERENCE NO. :
- 2041691
- LAST UPDATED :
- 199709
- DATA ITEMS CITED :
- 3
- MOLECULAR FORMULA :
- C8-H7-N-O2
- MOLECULAR WEIGHT :
- 149.16
- WISWESSER LINE NOTATION :
- QNU1VR
HEALTH HAZARD DATA
ACUTE TOXICITY DATA
- TYPE OF TEST :
- LDLo - Lowest published lethal dose
- ROUTE OF EXPOSURE :
- Oral
- SPECIES OBSERVED :
- Rodent - rat
- DOSE/DURATION :
- 100 mg/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- REFERENCE :
- NCNSA6 National Academy of Sciences, National Research Council, Chemical-Biological Coordination Center, Review. (Washington, DC) Volume(issue)/page/year: 5,27,1953
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Intraperitoneal
- SPECIES OBSERVED :
- Rodent - mouse
- DOSE/DURATION :
- 75 mg/kg
- TOXIC EFFECTS :
- Behavioral - coma
- REFERENCE :
- JPETAB Journal of Pharmacology and Experimental Therapeutics. (Williams & Wilkins Co., 428 E. Preston St., Baltimore, MD 21202) V.1- 1909/10- Volume(issue)/page/year: 119,522,1957
Safety Information
[ Symbol ]:
GHS07
[ Signal Word ]:
Warning
[ Hazard Statements ]:
H302-H312-H332
[ Precautionary Statements ]:
P280
[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves
[ Hazard Codes ]:
Xi:Irritant;
[ Risk Phrases ]:
R36/37/38
[ Safety Phrases ]:
S36/37-S24/25
[ RIDADR ]:
2811
[ WGK Germany ]:
3
[ RTECS ]:
MD3325000
[ HS Code ]:
2928000090
Synthetic Route
Precursor & DownStream
Precursor
DownStream
Customs
[ HS Code ]: 2928000090
[ Summary ]:
2928000090 other organic derivatives of hydrazine or of hydroxylamine VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:20.0%
Articles
Biotechnol. Lett. 34(7) , 1351-6, (2012)
Nicotiana tabacum cell suspensions, 2 g wet wt/ml, rapidly took up 1 mM isonitrosoacetophenone (INAP), a plant-derived stress metabolite with anti-oxidative and anti-fungal properties, producing 4'-he...
Neuropathy target esterase: rates of turnover in vivo following covalent inhibition with phenyl di-n-pentylphosphinate.J. Neurochem. 51(4) , 1097-101, (1988)
Phenyl di-n-pentylphosphinate is a reasonably stable easily synthesized inhibitor of neuropathy target esterase (NTE) with low anticholinesterase activity. Like phenylmethylsulphonyl fluoride it prote...
Synthesis and evaluation of 4-(3-methyl-2-butenoxy) isonitrosoacetophenone, a radiation-induced stress metabolite in Citrus.Phytochemistry 50(6) , 983-9, (1999)
The time- and dose-dependent occurrence of 4-(3-methyl-2-butenoxy)isonitrosoacetophenone, a gamma-irradiation-induced stress metabolite was investigated. The chemical synthesis of the compound is repo...