Benzenesulfenylchloride, 2,4-dinitro-
Names
[ CAS No. ]:
528-76-7
[ Name ]:
Benzenesulfenylchloride, 2,4-dinitro-
[Synonym ]:
MFCD00007129
EINECS 208-441-2
2,4-Dinitrobenzenesulfenyl Chloride
(2,4-dinitrophenyl) thiohypochlorite
Chemical & Physical Properties
[ Density]:
1.68g/cm3
[ Boiling Point ]:
430.1ºC at 760 mmHg
[ Melting Point ]:
94-97 °C(lit.)
[ Molecular Formula ]:
C6H3ClN2O4S
[ Molecular Weight ]:
234.61700
[ Flash Point ]:
213.9ºC
[ Exact Mass ]:
233.95000
[ PSA ]:
116.94000
[ LogP ]:
3.79530
[ Index of Refraction ]:
1.662
[ Storage condition ]:
Store at RT.
MSDS
Safety Information
[ Symbol ]:
GHS05
[ Signal Word ]:
Danger
[ Hazard Statements ]:
H314
[ Precautionary Statements ]:
P280-P305 + P351 + P338-P310
[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face particle respirator type N100 (US);Gloves;respirator cartridge type N100 (US);type P1 (EN143) respirator filter;type P3 (EN 143) respirator cartridges
[ Hazard Codes ]:
C
[ Risk Phrases ]:
34-37
[ Safety Phrases ]:
S26-S36/37/39-S45
[ RIDADR ]:
UN 3261 8/PG 2
[ WGK Germany ]:
3
[ Packaging Group ]:
III
[ Hazard Class ]:
8
[ HS Code ]:
2930909090
Synthetic Route
Precursor & DownStream
Precursor
DownStream
Customs
[ HS Code ]: 2930909090
[ Summary ]:
2930909090. other organo-sulphur compounds. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:30.0%
Articles
J. Biol. Chem. 256(11) , 5481-8, (1981)
The tryptophan residues on cholera toxin and its A and B protomers have been modified by reaction with 2-nitrophenylsulfenyl chloride and 2,4-dinitrophenylsulfenyl chloride. Modification of the trypto...
Involvement and identification of a tryptophanyl residue at the pyruvate binding site of transcarboxylase.Biochemistry 27(16) , 5978-83, (1988)
Transcarboxylase (TC) from Propionibacterium shermanii consists of a central hexameric 12S subunit to which 6 outer dimeric 5S subunits are attached through 12 biotinyl 1.3S subunits. The enzyme catal...
Studies on the Effect of Remote Substituents on Reactivity: The Rates of Addition of 2, 4-Dinitrobenzenesulfenyl Chloride to Cyclohexenes and Norbornenes (I) 1a. Kwart H and Miller LJ.J. Am. Chem. Soc. 83(22) , 4552-4559, (1961)