methyl ethyl acetoacetate
Names
[ CAS No. ]:
51756-08-2
[ Name ]:
methyl ethyl acetoacetate
[Synonym ]:
Methyl 2-ethylacetoacetate
methyl 2-ethyl-3-oxobutanoate
MFCD01632136
EINECS 257-381-3
Chemical & Physical Properties
[ Density]:
1.010 g/mL at 20 °C(lit.)
[ Boiling Point ]:
262.4ºC at 760mmHg
[ Molecular Formula ]:
C7H12O3
[ Molecular Weight ]:
144.16800
[ Flash Point ]:
96.1ºC
[ Exact Mass ]:
144.07900
[ PSA ]:
43.37000
[ LogP ]:
0.77460
[ Index of Refraction ]:
n20/D 1.423
MSDS
Safety Information
[ Personal Protective Equipment ]:
Eyeshields;Gloves
[ Hazard Codes ]:
Xi
[ Risk Phrases ]:
36/37/38
[ Safety Phrases ]:
23-24/25
[ RIDADR ]:
NONH for all modes of transport
[ WGK Germany ]:
3
[ HS Code ]:
2918300090
Synthetic Route
Precursor & DownStream
Precursor
DownStream
Customs
[ HS Code ]: 2918300090
[ Summary ]:
2918300090 other carboxylic acids with aldehyde or ketone function but without other oxygen function, their anhydrides, halides, peroxides, peroxyacids and their derivatives。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。MFN tariff:6.5%。General tariff:30.0%
Articles
Org. Lett. 8(5) , 935-8, (2006)
Polycyclic ring-fused 2-pyridones (5a-e and 9a-e) have been prepared via a microwave-assisted acyl-ketene imine cyclocondensation. Starting from 3,4-dihydroisoquinolines (4a-b) or 3,4-dihydroharman (8...