Ethyl-1-methylpiperidin-3-carboxylat

Names

[ Name ]:
Ethyl-1-methylpiperidin-3-carboxylat

[Synonym ]:
Ethyl 1-methyl-3-piperidinecarboxylate
Ethyl 1-Methylnipecotate
MFCD00006496
Ethyl 1-methylpiperidine-3-carboxylate
Ethyl-1-methylpiperidin-3-carboxylat
EINECS 225-951-0
3-Piperidinecarboxylic acid, 1-methyl-, ethyl ester
1-Methylnipecotic Acid Ethyl Ester
1-Methyl-3-piperidinecarboxylic Acid Ethyl Ester
1-Methylpiperidine-3-carboxylic acid ethyl ester
Ethyl N-methylpiperidine-3-carboxylate
Ethyl N-methyl piperidine-3-carboxylate

Chemical & Physical Properties

[ Density]:
1.0±0.1 g/cm3

[ Boiling Point ]:
211.1±33.0 °C at 760 mmHg

[ Molecular Formula ]:
C₉H₁₇NO₂

[ Molecular Weight ]:
171.237

[ Flash Point ]:
68.3±0.0 °C

[ Exact Mass ]:
171.125931

[ PSA ]:
29.54000

[ LogP ]:
1.25

[ Vapour Pressure ]:
0.2±0.4 mmHg at 25°C

[ Index of Refraction ]:
1.459

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
Eyeshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
Xi:Irritant;

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
S26-S36/37/39-S37/39

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

DownStream

Articles

Chiral NMR discrimination of piperidines and piperazines using (18-crown-6)-2,3,11,12-tetracarboxylic acid.

J. Org. Chem. 71(24) , 9178-82, (2006)

Enantiomeric discrimination is observed in the (1)H and (13)C NMR spectra of piperidines and piperazines in the presence of (-)-(18-crown-6)-2,3,11,12-tetracarboxylic acid. The amines are protonated b...