2-Methyl-4-nitroanisole

Names

[ Name ]:
2-Methyl-4-nitroanisole

[Synonym ]:
Benzene, 1-methoxy-2-methyl-4-nitro-
1-Methoxy-2-methyl-4-nitrobenzene
2-Methyl-4-nitroanisole
WNR C1 DO1
2-Methoxy-5-nitrotoluene
EINECS 256-748-5
Methyl 2-methyl-4-nitrophenyl ether
MFCD07787583

Chemical & Physical Properties

[ Density]:
1.2±0.1 g/cm3

[ Boiling Point ]:
283.0±20.0 °C at 760 mmHg

[ Melting Point ]:
61-64ºC(lit.)

[ Molecular Formula ]:
C₈H₉NO₃

[ Molecular Weight ]:
167.162

[ Flash Point ]:
136.7±23.8 °C

[ Exact Mass ]:
167.058243

[ PSA ]:
55.05000

[ LogP ]:
2.49

[ Vapour Pressure ]:
0.0±0.6 mmHg at 25°C

[ Index of Refraction ]:
1.538

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H302-H319

[ Precautionary Statements ]:
P305 + P351 + P338

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves

[ Hazard Codes ]:
Xn,Xi

[ Risk Phrases ]:
R22

[ Safety Phrases ]:
26-36

[ RIDADR ]:
NONH for all modes of transport

[ HS Code ]:
2909309090

Synthetic Route

Click to get detail synthetic route

Customs

[ HS Code ]: 2909309090

[ Summary ]:
2909309090 other aromatic ethers and their halogenated, sulphonated, nitrated or nitrosated derivatives VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:5.5% General tariff:30.0%

Articles

Studies on photochemical reaction of air pollutants. X. Identification of nitrophenols in suspended particulates. Nojima K, et al.

Chem. Pharm. Bull. 31(3) , 1047-1051, (1983)

Annihilation of aromatic cation radicals by ion-pair and radical pair collapse. Unusual solvent and salt effects in the competition for aromatic substitution. Sankararaman S, et al.

J. Am. Chem. Soc. 109(25) , 7824-7838, (1987)

5-Methyl-6-methoxy-8-(2'-diethylaminoethylamino)-quinoline1. Carmack M, et al.

J. Am. Chem. Soc. 68(8) , 1551-1552, (1946)