Cyclohexylboronicacid

Names

[ Name ]:
Cyclohexylboronicacid

[Synonym ]:
Acide cyclohexylboronique
Boronic acid,cyclohexyl
1-cyclohexylboronic acid
Cyclohexyl-dihydroxy-bor
MFCD01311824
Boronic acid, B-cyclohexyl-
Cyclohexylboronicacid
cyclohexyl-dihydroxy-borane
Cyclohexyl-dihydroxy-boran
Cyclohexylboronic acid
Cyclohexylboronsaeure
Cyclohexaneboronic acid

Chemical & Physical Properties

[ Density]:
1.0±0.1 g/cm3

[ Boiling Point ]:
252.4±23.0 °C at 760 mmHg

[ Melting Point ]:
122-123 °C

[ Molecular Formula ]:
C₆H₁₃BO₂

[ Molecular Weight ]:
127.977

[ Flash Point ]:
106.4±22.6 °C

[ Exact Mass ]:
128.100861

[ PSA ]:
40.46000

[ LogP ]:
1.90

[ Vapour Pressure ]:
0.0±1.1 mmHg at 25°C

[ Index of Refraction ]:
1.452

[ Storage condition ]:
Refrigerator (+4°C)

[ Water Solubility ]:
25 g/L

MSDS

Click to get detail MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :: GU7171000

CHEMICAL NAME :: Cyclohexaneboronic acid

CAS REGISTRY NUMBER :: 4441-56-9

BEILSTEIN REFERENCE NO. :: 1921820

LAST UPDATED :: 199612

DATA ITEMS CITED :: 1

MOLECULAR FORMULA :: C6-H13-B-O2

MOLECULAR WEIGHT :: 128.00

WISWESSER LINE NOTATION :: L6TJ ABQQ

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Intravenous

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 320 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: CSLNX* U.S. Army Armament Research & Development Command, Chemical Systems Laboratory, NIOSH Exchange Chemicals. (Aberdeen Proving Ground, MD 21010) Volume(issue)/page/year: NX#02141

Safety Information

[ Personal Protective Equipment ]:
Eyeshields;Gloves;type N95 (US);type P1 (EN143) respirator filter

[ Hazard Codes ]:
Xi:Irritant;

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
S37/39-S26

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

[ RTECS ]:
GU7171000

[ HS Code ]:
2931900090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

DownStream

Customs

[ HS Code ]: 2931900090

[ Summary ]:
2931900090. other organo-inorganic compounds. VAT:17.0%. Tax rebate rate:13.0%. Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward). MFN tariff:6.5%. General tariff:30.0%

Articles

Simultaneous Enantioseparation of Aldohexoses and Aldopentoses Derivatized With L-Tryptophanamide by Reversed Phase HPLC Using Butylboronic Acid as a Complexation Reagent of Monosaccharides.

Chirality 27 , 417-21, (2015)

Three aldohexoses, glucose, galactose, and mannose, and three aldopentoses, arabinose, xylose, and ribose, were derivatized with L-tryptophanamide (L-TrpNH2 ) under alkaline conditions. Using a basic ...