(+/-)-Mandelamide

[ Density]:
1.246 g/cm3

[ Boiling Point ]:
345.5ºC at 760 mmHg

[ Melting Point ]:
133-137ºC(lit.)

[ Molecular Formula ]:
C₈H₉NO₂

[ Molecular Weight ]:
151.16300

[ Flash Point ]:
162.7ºC

[ Exact Mass ]:
151.06300

[ PSA ]:
63.32000

[ LogP ]:
0.90560

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H302-H315-H319

[ Precautionary Statements ]:
P305 + P351 + P338

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves

[ Hazard Codes ]:
Xn: Harmful;

[ Risk Phrases ]:
22-36/37/38

[ Safety Phrases ]:
26-36

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

Precursor

DownStream

The mandelamide keto-enol system in aqueous solution. Generation of the enol by hydration of phenylcarbamoylcarbene.

J. Am. Chem. Soc. 125(1) , 187-94, (2003)

Flash photolysis of diazophenylacetamide in aqueous solution produced phenylcarbamoylcarbene, whose hydration generated a transient species that was identified as the enol isomer of mandelamide. This ...

[Molecular biology aspects of the antimicrobial effect of synthetic chemotherapeutic agents].

Z. Arztl. Fortbild. (Jena.) 76(15) , 662-6, (1982)

Catalytic asymmetric addition of dimethylzinc to alpha-ketoesters, using mandelamides as ligands.

Org. Lett. 8(7) , 1287-90, (2006)

[reaction: see text] A strategy based on the control of the electron-donating capabilities of the coordinating groups of the ligand has been applied in the catalytic asymmetric addition of organometal...

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