2-Difluoroacetic acid methyl ester
Names
[ CAS No. ]:
433-53-4
[ Name ]:
2-Difluoroacetic acid methyl ester
[Synonym ]:
Difluoroacetic Acid Methyl Ester
MFCD00039276
Methyl Difluoroacetate
methyl 2,2-difluoroacetate
EINECS 207-089-7
Chemical & Physical Properties
[ Density]:
1.2±0.1 g/cm3
[ Boiling Point ]:
45.0±25.0 °C at 760 mmHg
[ Molecular Formula ]:
C3H4F2O2
[ Molecular Weight ]:
110.060
[ Flash Point ]:
-16.9±18.1 °C
[ Exact Mass ]:
110.017937
[ PSA ]:
26.30000
[ LogP ]:
-0.12
[ Vapour Pressure ]:
354.3±0.1 mmHg at 25°C
[ Index of Refraction ]:
1.312
MSDS
Safety Information
[ Symbol ]:
GHS02, GHS07
[ Signal Word ]:
Warning
[ Hazard Statements ]:
H226-H302 + H312 + H332-H315-H319-H335
[ Precautionary Statements ]:
P261-P280-P305 + P351 + P338
[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter
[ Hazard Codes ]:
Xn: Harmful;
[ Risk Phrases ]:
R11;R20/21/22;R36/37/38
[ Safety Phrases ]:
S16-S23-S36/37/39
[ RIDADR ]:
UN 1993 3/PG 3
[ WGK Germany ]:
3
[ Packaging Group ]:
II
[ Hazard Class ]:
3
[ HS Code ]:
2915900090
Synthetic Route
Precursor & DownStream
Precursor
DownStream
Customs
[ HS Code ]: 2915900090
[ Summary ]:
2915900090 other saturated acyclic monocarboxylic acids and their anhydrides, halides, peroxides and peroxyacids; their halogenated, sulphonated, nitrated or nitrosated derivatives VAT:17.0% Tax rebate rate:9.0% Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward) MFN tariff:5.5% General tariff:30.0%
Articles
Environ. Sci. Technol. 44(7) , 2354-9, (2010)
A 1080 L environmental chamber with in situ FTIR spectroscopy detection was used to study the product distribution and the mechanism of the Cl-initiated photooxidation of a series of fluoroacetates. T...
Methyl difluoroacetate inhibits corrosion of aluminum cathode current collector for lithium ion cells. Kawamura T, et al.Electrochem. Solid-State Let. 8(9) , A459-A463, (2005)
Properties of carbon anodes and thermal stability in LiPF6/methyl difluoroacetate electrolyte. Ihara M, et al.
J. Electrochem. Soc. 150(11) , A1476-A1483, (2003)