Fluoroacetone

Names

[ CAS No. ]:
430-51-3

[ Name ]:
Fluoroacetone

[Synonym ]:
1-fluoroacetone
1-fluoropropane-2-one
fluoro-acetone
EINECS 207-064-0
2-Propanone,1-fluoro
Acetone,fluoro
1-fluoro-propan-2-one
Fluoroacetone
Mono-fluoroacetone
1-Fluoro-2-propanone
MFCD00000451

Chemical & Physical Properties

[ Density]:
1.054 g/mL at 25 °C(lit.)

[ Boiling Point ]:
75 °C(lit.)

[ Molecular Formula ]:
C₃H₅FO

[ Molecular Weight ]:
76.06960

[ Flash Point ]:
45 °F

[ Exact Mass ]:
76.03240

[ PSA ]:
17.07000

[ LogP ]:
0.54490

[ Vapour Pressure ]:
107mmHg at 25°C

[ Index of Refraction ]:
n20/D 1.37(lit.)

[ Storage condition ]:
Refrigerator (+4°C) + Flammables area

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS02, GHS06

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H225-H300 + H310 + H330

[ Precautionary Statements ]:
P210-P260-P264-P280-P284-P301 + P310

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
F,T+,T

[ Risk Phrases ]:
11-26/27/28

[ Safety Phrases ]:
16-36-45

[ RIDADR ]:
UN 2929 6.1/PG 1

[ WGK Germany ]:
3

[ RTECS ]:
SG1400000

[ Packaging Group ]:
II

[ Hazard Class ]:
6.1(a)

[ HS Code ]:
32041300

Synthetic Route

Click to get detail synthetic route

Customs

[ HS Code ]: 2914700090

[ Summary ]:
HS: 2914700090 halogenated, sulphonated, nitrated or nitrosated derivatives of ketones and quinones, whether or not with other oxygen function Tax rebate rate:9.0% Supervision conditions:none VAT:17.0% MFN tariff:5.5% General tariff:30.0%

Articles

13C NMR, infrared, solvation and theoretical investigation of the conformational isomerism in 1-haloacetones (X = Cl, Br and I).

Spectrochim. Acta. A. Mol. Biomol. Spectrosc. 61(9) , 2221-30, (2005)

The solvent dependence of the 13C NMR spectra of chloroacetone (CA), bromoacetone (BA) and iodoacetone (IA) are reported and the 3J(CH) couplings analysed using ab initio calculations and solvation th...

Lange A, et al.

J. Chem. Soc., Perkin Trans. II 7 , 1343-1350, (1999)

Organocatalyzed highly enantioselective direct aldol reactions of aldehydes with hydroxyacetone and fluoroacetone in aqueous media: the use of water to control regioselectivity.

Chemistry 13(2) , 689-701, (2007)

An organocatalyst prepared from (2R,3R)-diethyl 2-amino-3-hydroxysuccinate and L-proline exhibited high regio- and enantioselectivities for the direct aldol reactions of hydroxyacetone and fluoroaceto...