Bifenox

Names

[ Name ]:
Bifenox

[Synonym ]:
2,4-dichlorophenyl 3'-methoxycarbonyl-4'-nitrophenyl ether
Bifenox
5-(2,4-dichlorophenoxy)-2-nitrobenzoic acid methyl ester
Caswell No. 561AA
Benzoic acid,5-(2,4-dichlorophenoxy)-2-nitro-,methyl ester
methyl 2-nitro-5-(2',4'-dichlorophenoxy)benzoate
MFCD00055314
Methyl 5-(2,4-dichlorophenoxy)-2-nitrobenzoate
Benzoic acid, 5-(2,4-dichlorophenoxy)-2-nitro-, methyl ester
Modown
EINECS 255-894-7
methyl 5-(2',4'-dichlorophenoxy)-2-nitrobenzoate
2,4-Dichlorophenyl 3-(Methoxycarbonyl)-4-nitrophenyl Ether
Bifenox [ANSI:BSI:ISO]
MC-4379

Chemical & Physical Properties

[ Density]:
1.5±0.1 g/cm3

[ Boiling Point ]:
421.0±45.0 °C at 760 mmHg

[ Melting Point ]:
83 - 85ºC

[ Molecular Formula ]:
C₁₄H₉Cl₂NO₅

[ Molecular Weight ]:
342.131

[ Flash Point ]:
208.4±28.7 °C

[ Exact Mass ]:
340.985779

[ PSA ]:
81.35000

[ LogP ]:
4.52

[ Vapour Pressure ]:
0.0±1.0 mmHg at 25°C

[ Index of Refraction ]:
1.608

MSDS

Click to get detail MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :: DG7890000

CHEMICAL NAME :: Benzoic acid, 5-(2,4-dichlorophenoxy)-2-nitro-, methyl ester

CAS REGISTRY NUMBER :: 42576-02-3

LAST UPDATED :: 199710

DATA ITEMS CITED :: 6

MOLECULAR FORMULA :: C14-H9-Cl2-N-O5

MOLECULAR WEIGHT :: 342.14

WISWESSER LINE NOTATION :: GR CG DOR DNW CVO1

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 6400 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: 85ARAE "Agricultural Chemicals," Thomson, W.T., 4 vols., Fresno, CA, Thomson Publications, 1976/77 revision Volume(issue)/page/year: 2,15,1977

TYPE OF TEST :: LC50 - Lethal concentration, 50 percent kill

ROUTE OF EXPOSURE :: Inhalation

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: >200 gm/m3

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: DEVEAA Defense des Vegetaux. (Federation Nationale des Groupements de Protection des Cultures, 149, rue de Bercy, 75595 Paris Cedex, 12, France) V.1- 1947- Volume(issue)/page/year: 37,3,1983

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 4556 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: PEMNDP Pesticide Manual. (The British Crop Protection Council, 20 Bridport Rd., Thornton Heath CR4 7QG, UK) V.1- 1968- Volume(issue)/page/year: 9,71,1991

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Administration onto the skin

SPECIES OBSERVED :: Rodent - rabbit

DOSE/DURATION :: >20 gm/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: DEVEAA Defense des Vegetaux. (Federation Nationale des Groupements de Protection des Cultures, 149, rue de Bercy, 75595 Paris Cedex, 12, France) V.1- 1947- Volume(issue)/page/year: 37,3,1983 *** U.S. STANDARDS AND REGULATIONS *** EPA FIFRA 1988 PESTICIDE SUBJECT TO REGISTRATION OR RE-REGISTRATION FEREAC Federal Register. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) V.1- 1936- Volume(issue)/page/year: 54,7740,1989

Safety Information

[ Symbol ]:

GHS09

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H410

[ Precautionary Statements ]:
P273-P501

[ Personal Protective Equipment ]:
Eyeshields;Gloves;type N95 (US);type P1 (EN143) respirator filter

[ Hazard Codes ]:
N: Dangerous for the environment;

[ Risk Phrases ]:
50/53

[ Safety Phrases ]:
S60-S61

[ RIDADR ]:
UN 3077 9/PG 3

[ RTECS ]:
DG7890000

[ HS Code ]:
2918990090

Precursor & DownStream

Precursor

DownStream

Customs

[ HS Code ]: 2918990090

[ Summary ]:
2918990090. other carboxylic acids with additional oxygen function and their anhydrides, halides, peroxides and peroxyacids; their halogenated, sulphonated, nitrated or nitrosated derivatives. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:30.0%

Articles

Synthesis of aryl D-gluco- and D-galacto-pyranosides and 1-O-acyl-D-gluco- and -D-galacto-pyranoses exploiting the Mitsunobu reaction. Influence of the pKa of the acid on the stereoselectivity of the reaction.

Carbohydr. Res. 228(1) , 191-203, (1992)

Glycosides (alpha- and beta-D-glucosides and -D-galactosides) derived from three pesticides, 2-tert-butyl-2,4-dinitrophenol,2,6-dibromo-4-cyanophenol, and 5-(2,4-dichlorophenoxy)-2-nitrobenzoic acid, ...

Detection of mutagenicity of diphenyl ether herbicides in Salmonella typhimurium YG1026 and YG1021.

Mutat. Res. 346(1) , 57-60, (1995)

Three kinds of diphenyl ether herbicides, 4-nitrophenyl 2,4,6-trichlorophenyl ether (CNP, chlornitrofen), 2,4-dichlorophenyl 3-methoxy-4-nitrophenyl ether (chlomethoxynil) and 2,4-dichlorophenyl 3-met...

Developmental toxicity of diphenyl ether herbicides in nestling American kestrels.

J. Toxicol. Environ. Health A 34(3) , 323-36, (1991)

Beginning the day after hatching, American kestrel (Falco sparverius) nestlings were orally dosed for 10 consecutive days with 5 microliters/g of corn oil (controls) or one of the diphenyl ether herbi...

Related Compounds

The content on this webpage is sourced from various professional data sources. If you have any questions or concerns regarding the content, please feel free to contact service1@chemsrc.com.