Lithium diisopropylamide
Names
[ CAS No. ]:
4111-54-0
[ Name ]:
Lithium diisopropylamide
[Synonym ]:
2-Propanamine, N-(1-methylethyl)-, lithium salt (1:1)
LDA
Lithium diisopropylamide
lithium diisopropylamine
Lithium diisopropylamide solution
EINECS 223-893-0
UNII-OL028KIW1I
lithium N,N-diisopropylamide
Lithium diisopropylamide,LDA
Lithium diisopropylazanide
Lithium Diisopropylamide (LDA)
lithiumdiisopropylamide
lithium diisopropyl amide
MFCD00064449
lithium di(propan-2-yl)azanide
Chemical & Physical Properties
[ Density]:
0.864 g/mL at 25 °C(lit.)
[ Boiling Point ]:
65 °C
[ Melting Point ]:
38-42ºC
[ Molecular Formula ]:
C6H14LiN
[ Molecular Weight ]:
107.123
[ Flash Point ]:
91 °F
[ Exact Mass ]:
107.128632
[ PSA ]:
3.24000
[ LogP ]:
1.56950
[ Appearance of Characters ]:
liquid | brown
[ Vapour density ]:
>1 (vs air)
[ Storage condition ]:
2-8°C
[ Water Solubility ]:
decomposes
MSDS
Safety Information
[ Symbol ]:
GHS02, GHS05, GHS07, GHS08, GHS09
[ Signal Word ]:
Danger
[ Hazard Statements ]:
H225-H250-H302-H304-H314-H335-H336-H351-H361f-H373-H411
[ Supplemental HS ]:
May form explosive peroxides.
[ Precautionary Statements ]:
P210-P231-P280-P305 + P351 + P338-P370 + P378-P422
[ Hazard Codes ]:
F:Flammable;C:Corrosive;N:Dangerousfortheenvironment;
[ Risk Phrases ]:
R11;R14;R15;R19;R35;R51/53;R65;R67
[ Safety Phrases ]:
S26-S36/37/39-S43-S45-S60-S61-S62-S8-S16-S23-S33-S27
[ RIDADR ]:
UN 3399 4.3/PG 2
[ WGK Germany ]:
3
[ Packaging Group ]:
I
[ Hazard Class ]:
4.2
[ HS Code ]:
2924199090
Precursor & DownStream
Precursor
DownStream
Customs
[ HS Code ]: 2924199090
[ Summary ]:
2924199090. other acyclic amides (including acyclic carbamates) and their derivatives; salts thereof. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:30.0%
Articles
PLoS ONE 10 , e0120295, (2015)
Recent genome wide association studies have linked tribbles pseudokinase 1 (TRIB1) to the risk of coronary artery disease (CAD). Based on the observations that increased expression of TRIB1 reduces se...
Clinical relevance of vascular endothelial growth factor type A (VEGFA) and VEGF receptor type 2 (VEGFR2) gene polymorphism in chronic lymphocytic leukemia.Blood Cells Mol. Dis. 54(2) , 139-43, (2015)
Vascular endothelial growth factor type A (VEGFA) is a key regulator of angiogenesis and vascular permeability. Chronic lymphocytic leukemia (CLL) cells are able to secrete VEGFA and express VEGFA rec...
Pendant allyl crosslinking as a tunable shape memory actuator for vascular applications.Acta Biomater. 24 , 53-63, (2015)
Thermo-responsive shape memory polymers (SMPs) can be programmed to fit into small-bore incisions and recover their functional shape upon deployment in the body. This property is of significant intere...