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pentaethylenehexamine

Names

[ CAS No. ]:
4067-16-7

[ Name ]:
pentaethylenehexamine

[Synonym ]:
3,6,9,12-Tetraazatetradecane-1,14-diamine
pentaethylenehexamine
N'-[2-[2-[2-(2-aminoethylamino)ethylamino]ethylamino]ethyl]ethane-1,2-diamine
EINECS 223-775-9
MFCD00008167
N1,N1'-(Ethane-1,2-diyl)bis(N2-(2-aminoethyl)ethane-1,2-diamine)

Chemical & Physical Properties

[ Density]:
1.0±0.1 g/cm3

[ Boiling Point ]:
389.1±32.0 °C at 760 mmHg

[ Melting Point ]:
-35 °C

[ Molecular Formula ]:
C10H28N6

[ Molecular Weight ]:
232.370

[ Flash Point ]:
223.3±28.7 °C

[ Exact Mass ]:
232.237549

[ PSA ]:
100.16000

[ LogP ]:
-2.79

[ Vapour Pressure ]:
0.0±0.9 mmHg at 25°C

[ Index of Refraction ]:
1.503

[ Stability ]:
Stable. Incompatible with strong oxidizing agents, strong acids.

MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
RZ2680000
CHEMICAL NAME :
Pentaethylenehexamine
CAS REGISTRY NUMBER :
4067-16-7
BEILSTEIN REFERENCE NO. :
1768042
LAST UPDATED :
199701
DATA ITEMS CITED :
3
MOLECULAR FORMULA :
C10-H28-N6
MOLECULAR WEIGHT :
232.44
WISWESSER LINE NOTATION :
Z2M2M2M2M2Z

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
1600 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value

MUTATION DATA

TYPE OF TEST :
Mutation in microorganisms
TEST SYSTEM :
Bacteria - Salmonella typhimurium
DOSE/DURATION :
3333 ug/plate
REFERENCE :
ENMUDM Environmental Mutagenesis. (New York, NY) V.1-9, 1979-87. For publisher information, see EMMUEG. Volume(issue)/page/year: 8(Suupl 7),1,1986

Safety Information

[ Symbol ]:

GHS05, GHS07, GHS09

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H302 + H312-H314-H317-H410

[ Precautionary Statements ]:
P273-P280-P305 + P351 + P338-P310-P501

[ Personal Protective Equipment ]:
Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
C,N

[ Risk Phrases ]:
34-43-50/53

[ Safety Phrases ]:
S26-S36/37/39-S45-S60-S61

[ RIDADR ]:
UN 2735 8/PG 3

[ WGK Germany ]:
2

[ RTECS ]:
RZ2680000

[ Packaging Group ]:
III

[ Hazard Class ]:
8

[ HS Code ]:
2921290000

Synthetic Route

Precursor & DownStream

Customs

[ HS Code ]: 2921290000

[ Summary ]:
2921290000 other acyclic polyamines and their derivatives; salts thereof。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。MFN tariff:6.5%。General tariff:30.0%

Articles

Generation of a focused poly(amino ether) library: polymer-mediated transgene delivery and gold-nanorod based theranostic systems.

Theranostics 2 , 1160-73, (2013)

A focused library of twenty-one cationic poly(amino ethers) was synthesized following ring-opening polymerization of two diglycidyl ethers by different oligoamines. The polymers were screened in paral...

Chelating resin immobilizing carboxymethylated polyethyleneimine for selective solid-phase extraction of trace elements: Effect of the molecular weight of polyethyleneimine and its carboxymethylation rate.

Talanta 147 , 342-50, (2015)

The effect of the molecular weight of polyethyleneimine (PEI), defined as a compound having two or more ethyleneamine units, and of its carboxymethylation rate (CM/N), represented by the ratio of ion-...

Synthesis of homopolypeptides by aminolysis mediated by proteases encapsulated in silica nanospheres.

Macromol. Biosci. 14(11) , 1619-26, (2014)

We report the encapsulation of three different proteases in bioinspired silica. Silica particles were formed under mild reaction conditions using cationic amine-rich ethyleneamines as initiators, whic...


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