Dimethyl 2-allylmalonate

Names

[ Name ]:
Dimethyl 2-allylmalonate

[Synonym ]:
MFCD00014959
dimethyl 2-allylmalonate
EINECS 255-017-8
Dimethyl allylmalonate
Propanedioic acid, 2-propenyl-, dimethyl ester
Propanedioic acid, 2-(2-propen-1-yl)-, dimethyl ester
dimethyl 2-prop-2-enylpropanedioate

Chemical & Physical Properties

[ Density]:
1.1±0.1 g/cm3

[ Boiling Point ]:
165.2±20.0 °C at 760 mmHg

[ Melting Point ]:
<-80ºC

[ Molecular Formula ]:
C₈H₁₂O₄

[ Molecular Weight ]:
172.178

[ Flash Point ]:
67.3±20.2 °C

[ Exact Mass ]:
172.073563

[ PSA ]:
52.60000

[ LogP ]:
0.93

[ Vapour Pressure ]:
1.9±0.3 mmHg at 25°C

[ Index of Refraction ]:
1.433

MSDS

Click to get detail MSDS

Safety Information

[ Personal Protective Equipment ]:
Eyeshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
Xi

[ Risk Phrases ]:
36/37/38

[ Safety Phrases ]:
S23-S24/25

[ WGK Germany ]:
3

[ HS Code ]:
2917190090

Precursor & DownStream

Precursor

DownStream

Customs

[ HS Code ]: 2917190090

[ Summary ]:
2917190090 acyclic polycarboxylic acids, their anhydrides, halides, peroxides, peroxyacids and their derivatives VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:30.0%

Articles

Tandem cyclization/hydrosilylation of functionalized 1, 6-dienes catalyzed by a cationic palladium complex. Widenhoefer RA and DeCarli MA.

J. Am. Chem. Soc. 120(15) , 3805-3806, (1998)

Synthesis of substituted cyclopentenes from the Baylis-Hillman adducts via ring-closing metathesis reaction. Lee KY, et al.

Bull. Korean Chem. Soc. 25(8) , 1280-1282, (2004)

The study of intramolecular free radical cyclizations of a-sulfonyl and a-sulfinyl radicals. Yeun-Min T, et al.

Tetrahedron Lett. 31(42) , 6047-6050, (1990)