6-Fluoro-2H-1,4-benzoxazin-3(4H)-one
Names
[ CAS No. ]:
398-63-0
[ Name ]:
6-Fluoro-2H-1,4-benzoxazin-3(4H)-one
[Synonym ]:
MFCD03424565
6-Fluoro-2H-1,4-benzoxazin-3(4H)-one
6-fluoro-2,4-dihydro-1,4-benzoxazin-3-one
2H-1,4-Benzoxazin-3(4H)-one, 6-fluoro-
Chemical & Physical Properties
[ Density]:
1.3±0.1 g/cm3
[ Boiling Point ]:
322.9±42.0 °C at 760 mmHg
[ Melting Point ]:
207-211ºC(lit.)
[ Molecular Formula ]:
C8H6FNO2
[ Molecular Weight ]:
167.137
[ Flash Point ]:
149.1±27.9 °C
[ Exact Mass ]:
167.038254
[ PSA ]:
38.33000
[ LogP ]:
1.09
[ Vapour Pressure ]:
0.0±0.7 mmHg at 25°C
[ Index of Refraction ]:
1.540
MSDS
Safety Information
[ Symbol ]:
GHS07
[ Signal Word ]:
Warning
[ Hazard Statements ]:
H315-H319-H335
[ Precautionary Statements ]:
P261-P305 + P351 + P338
[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves
[ Hazard Codes ]:
Xi
[ Risk Phrases ]:
R36/37/38
[ Safety Phrases ]:
S26-S36
[ RIDADR ]:
NONH for all modes of transport
[ HS Code ]:
2934999090
Synthetic Route
Precursor & DownStream
Precursor
DownStream
Customs
[ HS Code ]: 2934999090
[ Summary ]:
2934999090. other heterocyclic compounds. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%
Articles
J. Agric. Food Chem. 54(26) , 9843-51, (2006)
The utility of benzoxazinones and some of their synthetic derivatives in the search for new leads for herbicide model development has been widely discussed. As the benzoxazinone skeleton contains thre...
Peroxidase-catalyzed halide ion oxidation.Redox Rep. 5(4) , 169-71, (2000)
The first complete mechanistic analysis of halide ion oxidation by a peroxidase was that of iodide oxidation by horseradish peroxidase. It was shown conclusively that a two-electron oxidation of iodid...
The proximate coupling constant, 5 J (H, CH3), and the torsional mobility of the thiomethyl group in some thioanisole derivatives. Schaefer T, et al.Can. J. Chem. 69(4) , 620-624, (1991)