2,4-Dichloro-6-methoxy-1,3,5-triazine

Names

[ Name ]:
2,4-Dichloro-6-methoxy-1,3,5-triazine

[Synonym ]:
2,6-dichloro-4-methoxy-1,3,5-triazine
MFCD00128159
2,4-dichloro-6-methoxy-s-triazine
2-methoxy-4,6-dichloro-1,3,5-triazine
EINECS 222-863-4

Chemical & Physical Properties

[ Density]:
1.538 g/cm3

[ Boiling Point ]:
132-134 °C49 mm Hg(lit.)

[ Melting Point ]:
86-88 °C(lit.)

[ Molecular Formula ]:
C₄H₃Cl₂N₃O

[ Molecular Weight ]:
179.99200

[ Flash Point ]:
157.2ºC

[ Exact Mass ]:
178.96500

[ PSA ]:
47.90000

[ LogP ]:
1.18700

[ Index of Refraction ]:
1.545

[ Storage condition ]:
2-8°C

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves

[ Hazard Codes ]:
Xi:Irritant;

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
S26-S37/39

[ RIDADR ]:
UN 3335

[ WGK Germany ]:
3

[ HS Code ]:
2933699090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

DownStream

Customs

[ HS Code ]: 2933699090

[ Summary ]:
2933699090 other compounds containing an unfused triazine ring (whether or not hydrogenated) in the structure。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。MFN tariff:6.5%。General tariff:20.0%

Articles

An easy-to-use excimer fluorescence derivatization reagent, 2-chloro-4-methoxy-6-(4-(pyren-4-yl)butoxy)-1,3,5-triazine, for use in the highly sensitive and selective liquid chromatography analysis of histamine in Japanese soy sauces.

Anal. Chim. Acta 880 , 145-51, (2015)

In this study, a novel pre-column excimer fluorescence derivatization reagent, 2-chloro-4-methoxy-6-(4-(pyren-4-yl)butoxy)-1,3,5-triazine (CMPT), was developed for polyamines, specifically histamine. ...

Synthesis of alpha-cyclodextrin [2]-rotaxanes using chlorotriazine capping reagents.

Org. Biomol. Chem. 6(10) , 1814-21, (2008)

Ten alpha-cyclodextrin [2]-rotaxanes have been prepared with alkane-, stilbene- and azobenzene-based axles, capped through nucleophilic substitution of either 2-chloro-4,6-dimethoxy-1,3,5-triazine or ...

Design of chiral monochloro-s-triazine reagents for the liquid chromatographic separation of amino acid enantiomers.

J. Chromatogr. A. 998(1-2) , 73-82, (2003)

A series of chiral derivatizing reagents (CDRs) was synthesized by nucleophilic replacement of one chlorine atom in cyanuric chloride (2,4,6-trichloro-1,3,5-triazine; s-triazine) by alkoxy (methoxy, b...