1-Methyl-3-phenoxybenzene

Names

[ Name ]:
1-Methyl-3-phenoxybenzene

[Synonym ]:
Phenyl m-tolyl ether
EINECS 222-716-4
3-Methyldiphenyl Ether
1-Methyl-3-phenoxybenzene
3-Phenoxytoluene
3-methyl diphenyl ether
Benzene, 1-methyl-3-phenoxy-
m-Methylphenyl phenyl ether
BENZENE,1-METHYL-3-PHENOXY
3-Methylphenyl phenyl ether
meta-phenoxy-toluene
m-Phenoxytoluene
Ether,phenyl m-tolyl
m-Tolyl Phenyl Ether
MFCD00008531

Chemical & Physical Properties

[ Density]:
1.0±0.1 g/cm3

[ Boiling Point ]:
269.1±9.0 °C at 760 mmHg

[ Molecular Formula ]:
C₁₃H₁₂O

[ Molecular Weight ]:
184.234

[ Flash Point ]:
110.8±14.4 °C

[ Exact Mass ]:
184.088821

[ PSA ]:
9.23000

[ LogP ]:
4.67

[ Vapour Pressure ]:
0.0±0.5 mmHg at 25°C

[ Index of Refraction ]:
1.566

MSDS

Click to get detail MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :: DA6142000

CHEMICAL NAME :: Benzene, 1-methyl-3-phenoxy-

CAS REGISTRY NUMBER :: 3586-14-9

BEILSTEIN REFERENCE NO. :: 2045714

LAST UPDATED :: 199710

DATA ITEMS CITED :: 7

MOLECULAR FORMULA :: C13-H12-O

MOLECULAR WEIGHT :: 184.25

WISWESSER LINE NOTATION :: 1R COR

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 2509 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Administration onto the skin

SPECIES OBSERVED :: Rodent - rabbit

DOSE/DURATION :: >5 gm/kg

TOXIC EFFECTS :: Lungs, Thorax, or Respiration - acute pulmonary edema

MUTATION DATA

TYPE OF TEST :: Mutation in microorganisms

TEST SYSTEM :: Bacteria - Salmonella typhimurium

DOSE/DURATION :: 50 ug/plate

REFERENCE :: CHYCDW Zhonghua Yufangyixue Zazhi. Chinese Journal of Preventive Medicine. (China International Book Trading Corp., POB 2820, Beijing, Peop. Rep. China) Beginning history not known. Volume(issue)/page/year: 21,240,1987 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - X3741 No. of Facilities: 36 (estimated) No. of Industries: 1 No. of Occupations: 1 No. of Employees: 145 (estimated) No. of Female Employees: 73 (estimated)

Safety Information

[ Personal Protective Equipment ]:
Eyeshields;Gloves

[ Safety Phrases ]:
S23-S24/25

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
2

[ RTECS ]:
DA6142000

[ HS Code ]:
2909309090

Synthetic Route

Click to get detail synthetic route

Customs

[ HS Code ]: 2909309090

[ Summary ]:
2909309090 other aromatic ethers and their halogenated, sulphonated, nitrated or nitrosated derivatives VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:5.5% General tariff:30.0%

Articles

Metabolism of 3-methyldiphenyl ether by Sphingomonas sp. SS31.

FEMS Microbiol. Lett. 75(2-3) , 253-8, (1992)

The bacterium Sphingomonas sp. SS31, which was obtained from the diphenyl ether-degrading strain Sphingomonas sp. SS3 by an adaptation process, utilized 3-methyldiphenyl ether for growth in addition t...

First steps towards a Zn/Co(III)sep-driven P450 BM3 reactor.

Appl. Microbiol. Biotechnol. 91(4) , 989-99, (2011)

Cytochrome P450s are synthetically attractive hydroxylation catalysts. For cell-free applications, a constant supply of NAD(P)H can be very costly. Mediators such as Zn/Co(III)sep can be an alternativ...

Related Compounds

The content on this webpage is sourced from various professional data sources. If you have any questions or concerns regarding the content, please feel free to contact service1@chemsrc.com.