2-Chloro-4,6-dinitroaniline

Names

[ Name ]:
2-Chloro-4,6-dinitroaniline

[Synonym ]:
ANILINE,6-CHLORO-2,4-DINITRO
2,4-dinitro-6-chloroaniline
MFCD00075113
Benzenamine, 2-chloro-4,6-dinitro-
EINECS 222-564-9
Benzenamine,2-chloro-4,6-dinitro
2-Chloro-4,6-dinitroaniline
6-chloro-2,4-nitroaniline
6-Chloro-2,4-dinitroaniline

Chemical & Physical Properties

[ Density]:
1.7±0.1 g/cm3

[ Boiling Point ]:
376.3±37.0 °C at 760 mmHg

[ Melting Point ]:
157-159 °C(lit.)

[ Molecular Formula ]:
C₆H₄ClN₃O₄

[ Molecular Weight ]:
217.567

[ Flash Point ]:
181.4±26.5 °C

[ Exact Mass ]:
216.989029

[ PSA ]:
117.66000

[ LogP ]:
3.38

[ Vapour Pressure ]:
0.0±0.9 mmHg at 25°C

[ Index of Refraction ]:
1.686

MSDS

Click to get detail MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :: BX1226000

CHEMICAL NAME :: Aniline, 6-chloro-2,4-dinitro-

CAS REGISTRY NUMBER :: 3531-19-9

BEILSTEIN REFERENCE NO. :: 2463157

LAST UPDATED :: 199710

DATA ITEMS CITED :: 3

MOLECULAR FORMULA :: C6-H4-Cl-N3-O4

MOLECULAR WEIGHT :: 217.58

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

MUTATION DATA

TYPE OF TEST :: Mutation in microorganisms

TEST SYSTEM :: Bacteria - Salmonella typhimurium

DOSE/DURATION :: 500 ug/plate

REFERENCE :: SAIGBL Sangyo Igaku. Japanese Journal of Industrial Health. (Nippon Sangyo Eisei Igakkai, Kosu Eisei Bldg., 1-29-8, Shinjuku, Shinjuku-ku, Tokyo 160, Japan) V.1- 1959- Volume(issue)/page/year: 29,34,1987

Safety Information

[ Symbol ]:

GHS06, GHS08, GHS09

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H300 + H310 + H330-H373-H411

[ Precautionary Statements ]:
P260-P264-P273-P280-P284-P301 + P310

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves

[ Hazard Codes ]:
Xn:Harmful;

[ Risk Phrases ]:
R20/21/22;R36/37/38

[ Safety Phrases ]:
S26-S28-S36/37/39-S45

[ RIDADR ]:
UN 2811 6.1/PG 3

[ WGK Germany ]:
3

[ RTECS ]:
BX9250000

[ Packaging Group ]:
III

[ Hazard Class ]:
6.1

[ HS Code ]:
2921420090

Synthetic Route

Click to get detail synthetic route

Customs

[ HS Code ]: 2921420090

[ Summary ]:
HS:2921420090 aniline derivatives and their salts VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:30.0%

Articles

Sorting of polymorphs based on mechanical properties. Trimorphs of 6-chloro-2,4-dinitroaniline.

Chem. Commun. (Camb.) (19) , 2439-41, (2005)

Mechanical shearing of crystals of a polymorph with a layered structure may be used to separate them from harder crystals of a visually indistinguishable polymorph that resist such shearing.

Molecular crystals: pinching polymorphs.

Nat. Mater. 4(6) , 427-8, (2005)