N-BOC-aniline

Names

[ Name ]:
N-BOC-aniline

[Synonym ]:
Carbanilic acid,tert-butyl ester
phenyl-carbamic acid tert-butyl ester
N-tert-butoxycarbonylaniline
tert-butyl phenylcarbamate
N-BOC-aniline
Carbamic acid,phenyl-,1,1-dimethylethyl ester
Carbanilic acid tert-butyl ester
Carbamic acid, phenyl-, 1,1-dimethylethyl ester
tert-Butyl-N-phenylcarbamate
tert-Butyl Carbanilate
2-Methyl-2-propanyl phenylcarbamate
MFCD00043723
Carbamic acid, N-phenyl-, 1,1-dimethylethyl ester

Chemical & Physical Properties

[ Density]:
1.1±0.1 g/cm3

[ Boiling Point ]:
235.3±9.0 °C at 760 mmHg

[ Melting Point ]:
133-137 °C(lit.)

[ Molecular Formula ]:
C₁₁H₁₅NO₂

[ Molecular Weight ]:
193.242

[ Flash Point ]:
96.1±18.7 °C

[ Exact Mass ]:
193.110275

[ PSA ]:
38.33000

[ LogP ]:
3.00

[ Vapour Pressure ]:
0.1±0.5 mmHg at 25°C

[ Index of Refraction ]:
1.542

MSDS

Click to get detail MSDS

Safety Information

[ Personal Protective Equipment ]:
Eyeshields;Gloves;type N95 (US);type P1 (EN143) respirator filter

[ Hazard Codes ]:
Xi

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

[ HS Code ]:
2924299090

Synthetic Route

Click to get detail synthetic route

Customs

[ HS Code ]: 2924299090

[ Summary ]:
2924299090. other cyclic amides (including cyclic carbamates) and their derivatives; salts thereof. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:30.0%

Articles

Total synthesis of the polycyclic fungal metabolite (+/-)-communesin F.

Angew. Chem. Int. Ed. Engl. 49(11) , 2000-3, (2010)

Directed ortho lithiation of phenylcarbamic acid 1, 1-dimethylethyl ester (N-BOC-aniline). Revision and improvements. Stanetty P, et al.

J. Org. Chem. 57(25) , 6833-37, (1992)

Catalyst-free water-mediated N-Boc deprotection. Wang G, et al.

Tetrahedron Lett. 50(13) , 1438-1440, (2009)