3,5-DI-TERT-BUTYL-O-BENZOQUINONE
Names
[ CAS No. ]:
3383-21-9
[ Name ]:
3,5-DI-TERT-BUTYL-O-BENZOQUINONE
[Synonym ]:
3,5-Di-tert-butyl-1,2-benzoquinone
o-Benzoquinone,3,5-di-tert-butyl
o-Benzoquinone, 3,5-di-tert-butyl-
MFCD00001647
3,5-Ditert-butylbenzo-1,2-quinone
3,5-Cyclohexadiene-1,2-dione, 3,5-bis(1,1-dimethylethyl)-
3,5-di-tert-butylbenzo-1,2-quinone
3,5-di-tert-butylcyclohexa-3,5-diene-1,2-dione
EINECS 222-189-0
3,5-DI-TERT-BUTYL-O-BENZOQUINONE
3,5-di-t-butyl-o-benzoquinone
3,5-Bis(2-methyl-2-propanyl)-1,2-benzoquinone
Chemical & Physical Properties
[ Density]:
1.0±0.1 g/cm3
[ Boiling Point ]:
302.7±15.0 °C at 760 mmHg
[ Melting Point ]:
112-114 °C(lit.)
[ Molecular Formula ]:
C14H20O2
[ Molecular Weight ]:
220.307
[ Flash Point ]:
120.6±6.0 °C
[ Exact Mass ]:
220.146332
[ PSA ]:
34.14000
[ LogP ]:
3.04
[ Vapour Pressure ]:
0.0±0.6 mmHg at 25°C
[ Index of Refraction ]:
1.504
[ Stability ]:
Stable. Incompatible with reducing agents, strong oxidizing agents.
MSDS
Safety Information
[ Personal Protective Equipment ]:
Eyeshields;Gloves;type N95 (US);type P1 (EN143) respirator filter
[ Hazard Codes ]:
Xi
[ Risk Phrases ]:
36/37/38
[ Safety Phrases ]:
S22-S24/25
[ RIDADR ]:
NONH for all modes of transport
[ WGK Germany ]:
3
[ HS Code ]:
2914690090
Synthetic Route
Customs
[ HS Code ]: 2914690090
[ Summary ]:
2914690090 other quinones。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。MFN tariff:5.5%。General tariff:30.0%
Articles
Dalton Trans. 41(48) , 14498-513, (2012)
The title complexes reacted readily with the methylating agents MeI and CF(3)SO(3)Me, chalcogens (O(2), S(8)) and borane adducts BH(3)·L (L = THF, N(t)Bu(3), PPh(3)) to initially give the correspondin...
Versatile chemical transformations of benzoxazole based ligands on complexation with 3d-metal ions.Inorg. Chem. 51(4) , 2588-96, (2012)
Two benzoxazoles derivative ligands were synthesized from the condensation of 3,5-di-tert-butyl-o-benzoquinone (DTBBQ) with ethanolamine or 1,3-diamino-2-hydroxypropane in methanol. Condensation of DT...
Determination of natural thiols by liquid chromatography after derivatization with 3,5-di-tert.-butyl-1,2-benzoquinone.J. Chromatogr. A. 420(2) , 404-10, (1987)