3-Bromothioanisole
Names
[ CAS No. ]:
33733-73-2
[ Name ]:
3-Bromothioanisole
[Synonym ]:
3-Bromothioanisole
MFCD00041395
1-Bromo-2-(methylsulfanyl)benzene
3-Bromophenyl methyl sulphide
2-(methylthio)bromo benzene
Benzene, 1-bromo-3-(methylthio)-
Benzene, 1-bromo-2-(methylthio)-
3-methylthio-1-bromobenzene
3-Bromophenyl methyl sulfide
1-Bromo-3-(methylsulfanyl)benzene
1-bromo-3-methylsulfanyl-benzene
2-Bromophenyl methyl sulfide
3-bromo thioanisole
1-bromo-3-methylsulphanyl-benzene
1-Bromo-3-(methylthio)benzene
o-Bromo(methylthio)benzene
Chemical & Physical Properties
[ Density]:
1.5±0.1 g/cm3
[ Boiling Point ]:
237.4±23.0 °C at 760 mmHg
[ Molecular Formula ]:
C7H7BrS
[ Molecular Weight ]:
203.100
[ Flash Point ]:
97.4±22.6 °C
[ Exact Mass ]:
201.945175
[ PSA ]:
25.30000
[ LogP ]:
3.46
[ Vapour Pressure ]:
0.1±0.5 mmHg at 25°C
[ Index of Refraction ]:
1.624
MSDS
Safety Information
[ Personal Protective Equipment ]:
Eyeshields;Gloves;half-mask respirator (US);multi-purpose combination respirator cartridge (US)
[ Hazard Codes ]:
Xi: Irritant;
[ Risk Phrases ]:
R36/38
[ Safety Phrases ]:
S23-S24/25
[ RIDADR ]:
UN 3334
[ WGK Germany ]:
3
[ HS Code ]:
2930909090
Synthetic Route
Precursor & DownStream
Precursor
DownStream
Customs
[ HS Code ]: 2930909090
[ Summary ]:
2930909090. other organo-sulphur compounds. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:30.0%
Articles
J. Am. Chem. Soc. 124(9) , 1897-1901, (2002)
Enhancement of acid photogeneration through a para-to-meta substitution strategy in a sulfonium-based alkoxystilbene designed for two-photon polymerization. Xia R, et al.
Chem. Mater. 24(2) , 237-244, (2012)
Transition-Metal-Free Acid-Mediated Synthesis of Aryl Sulfides from Thiols and Thioethers. Wagner AM and Sanford MS.
J. Org. Chem. 79(5) , 2263-2267, (2014)