1-Bromo-2,4,5-trifluorobenzene

Names

[ CAS No. ]:
327-52-6

[ Name ]:
1-Bromo-2,4,5-trifluorobenzene

[Synonym ]:
2,4,5-TRIFLUOROBENZOBROMIDE
1-bromo-2,4,5-trifluoro-benzene
Benzene, 1-bromo-2,4,5-trifluoro-
MFCD00000306
1-Bromo-2,4,5-triflu
1,2,4-Trifluoro-5-bromobenzene
FR BF DF EE
2,4,5-trifluorophenyl bromide
1-Brom-2,4,5-trifluor-benzol
EINECS 206-318-8
1-Bromo-2,4,5-trifluorobenzene
2,4,5-Trifluorobromobenzene
2-BROMO-1,4,5-TRIFLUOROBENZENE
5-bromo-1,2,4-trifluorobenzene

Chemical & Physical Properties

[ Density]:
1.8±0.1 g/cm3

[ Boiling Point ]:
144.0±0.0 °C at 760 mmHg

[ Melting Point ]:
−19 °C(lit.)

[ Molecular Formula ]:
C₆H₂BrF₃

[ Molecular Weight ]:
210.979

[ Flash Point ]:
55.6±0.0 °C

[ Exact Mass ]:
209.929184

[ LogP ]:
3.00

[ Vapour Pressure ]:
6.5±0.2 mmHg at 25°C

[ Index of Refraction ]:
1.486

[ Water Solubility ]:
insoluble

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS02, GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H226-H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
Eyeshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
Xi:Irritant

[ Risk Phrases ]:
R10;R36/37/38

[ Safety Phrases ]:
S26-S36/37/39-S37/39-S16

[ RIDADR ]:
UN 1993 3/PG 3

[ WGK Germany ]:
3

[ Packaging Group ]:
III

[ Hazard Class ]:
3

[ HS Code ]:
2903999090

Precursor & DownStream

Precursor

DownStream

Customs

[ HS Code ]: 2903999090

[ Summary ]:
2903999090 halogenated derivatives of aromatic hydrocarbons VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:5.5% General tariff:30.0%

Articles

Bromine-magnesium-exchange as a general tool for the preparation of polyfunctional aryl and heteroaryl magnesium-reagents. Abarbri M, et al.

Tetrahedron Lett. 40(42) , 281-4, (1999)

3-Ethenyl, 3-ethynyl, 3-aryl, and 3-cyclopropyl-2, 4, 5-trifluorobenzoic acids: Useful intermediate in the synthesis of quinolone antibacterials. Turner WR and Suto MJ.

Tetrahedron Lett. 34(2) , 281-4, (1993)

A dramatic solvent effect during aromatic halogen-metal exchanges. Different products from lithiation of polyfluorobromobenzenes in ether and tetrahydrofuran. Bridges AJ, et al.

J. Org. Chem. 55(2) , 773-5, (1990)