Methyl Piperidine-2-carboxylate

Names

[ Name ]:
Methyl Piperidine-2-carboxylate

[Synonym ]:
MFCD00192316
piperidine-2-carboxylic acid methyl ester hydrochloride
2-Piperidinecarboxylic acid, methyl ester, hydrochloride (1:1)
methyl piperidine-2-carboxylate hydrochloride
Methyl 2-piperidinecarboxylate hydrochloride (1:1)
L-pipecolic acid methyl ester hydrochloride
Methyl pipecolinate hydrochloride
DL-pipecolic acid methyl ester hydrochloride
Methyl 2-piperidinecarboxylate hydrochloride
(S)-pipecolic acid methyl ester hydrochloride
2-piperidine-carboxylic acid methyl ester hydrochloride
Methy pipecolinate HCl
Methyl Piperidine-2-carboxylate

Chemical & Physical Properties

[ Boiling Point ]:
235.3ºC at 760 mmHg

[ Melting Point ]:
205ºC (dec.)(lit.)

[ Molecular Formula ]:
C₇H₁₄ClNO₂

[ Molecular Weight ]:
179.645

[ Flash Point ]:
96.1ºC

[ Exact Mass ]:
179.071304

[ PSA ]:
38.33000

[ LogP ]:
1.43230

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves

[ Hazard Codes ]:
Xi

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
26-37/39

[ RIDADR ]:
NONH for all modes of transport

[ HS Code ]:
2933399090

Precursor & DownStream

Precursor

DownStream

Customs

[ HS Code ]: 2933399090

[ Summary ]:
2933399090. other compounds containing an unfused pyridine ring (whether or not hydrogenated) in the structure. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%

Articles

Aldehyde-based racemization in the dynamic kinetic resolution of N-heterocyclic a-amino esters using Candida Antarctica lipase A. Liljeblad A, et al.

Tetrahedron 60(3) , 671-677, (2004)

Enantioselective lipase-catalyzed reactions of methyl pipecolinate: transesterification and N-acylation. Liljeblad, A, et al.

Tetrahedron Lett. 43(13) , 2471-2474, (2002)

The α-effect in cyclic secondary amines: new scaffolds for iminium ion accelerated transformations. Brazier JB, et al.

Tetrahedron 65(48) , 9961-9966, (2009)

Related Compounds

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