molecular sieves

[ Molecular Formula ]:
KnNa₁₂-n[(AlO₂)₁₂(SiO₂)₁₂]xH₂O

[ Appearance of Characters ]:
Powder or Crystals | Yellow to yellow-green

[ Water Solubility ]:
Insoluble in water.

[ Personal Protective Equipment ]:
Eyeshields;Gloves;type N95 (US);type P1 (EN143) respirator filter

[ Hazard Codes ]:
Xi,Xn

[ Risk Phrases ]:
36/37/38-20

[ Safety Phrases ]:
26-36

[ RIDADR ]:
NONH for all modes of transport

Synthesis of biaryls via catalytic decarboxylative coupling.

Science 313 , 662, (2006)

We present a safe and convenient cross-coupling strategy for the large-scale synthesis of biaryls, commercially important structures often found in biologically active molecules. In contrast to tradit...

Chiral phosphoric acid catalyzed enantioselective Friedel-Crafts alkylation of indoles with nitroalkenes: cooperative effect of 3 A molecular sieves.

Angew. Chem. Int. Ed. Engl. 47(21) , 4016-8, (2008)

Unexpected roles of molecular sieves in palladium-catalyzed aerobic alcohol oxidation.

J. Org. Chem. 71(5) , 1861-8, (2006)

Methods for palladium-catalyzed aerobic oxidation of alcohols often benefit from the presence of molecular sieves. This report explores the effect of molecular sieves on the Pd(OAc)2/pyridine and Pd(O...

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