P-TOLYL TRIFLATE

[ Density]:
1.342 g/mL at 25ºC(lit.)

[ Boiling Point ]:
115ºC50 mm Hg(lit.)

[ Molecular Formula ]:
C₈H₇F₃O₃S

[ Molecular Weight ]:
240.20000

[ Flash Point ]:
192 °F

[ Exact Mass ]:
240.00700

[ PSA ]:
51.75000

[ LogP ]:
3.30420

[ Vapour Pressure ]:
0.0242mmHg at 25°C

[ Index of Refraction ]:
n20/D 1.441(lit.)

Click to get detail MSDS

[ Symbol ]:

GHS05, GHS06, GHS08

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H301-H311-H314-H331-H351

[ Precautionary Statements ]:
P261-P280-P301 + P310-P305 + P351 + P338-P310

[ Personal Protective Equipment ]:
Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
T: Toxic;

[ Risk Phrases ]:
23/24/25-34-40

[ Safety Phrases ]:
16-26-36/37/39-45

[ RIDADR ]:
UN 3265 8/PG 2

[ HS Code ]:
2904909090

Click to get detail synthetic route

Precursor

DownStream

[ HS Code ]: 2904909090

[ Summary ]:
HS:2904909090 sulphonated, nitrated or nitrosated derivatives of hydrocarbons, whether or not halogenated VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:5.5% General tariff:30.0%

Enantioselective alpha-arylation of ketones with aryl triflates catalyzed by difluorphos complexes of palladium and nickel.

J. Am. Chem. Soc. 130(1) , 195-200, (2008)

The asymmetric alpha-arylation of ketones with aryl triflates is described, and the use of this electrophile with nickel and palladium catalysts containing a segphos derivative increases substantially...

Direct arylation of azine N-oxides with aryl triflates. Schipper DJ, et al.

Tetrahedron 65(26) , 4977-4983, (2009)

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