2-|tert|-Butyl-1,1,3,3-tetramethylguanidine
Names
[ CAS No. ]:
29166-72-1
[ Name ]:
2-|tert|-Butyl-1,1,3,3-tetramethylguanidine
[Synonym ]:
2-tert-butyl-1,1',3,3'-tetramethylguanidine
Barton's base
((CH3)2N)2C=N(t-C4H9)
1,1,3,3-tetramethyl-2-t-butylguanidine
N''-(1,1-dimethylethyl)-N,N,N',N'-tetramethylguanidine
MFCD01862972
Chemical & Physical Properties
[ Density]:
0.84g/cm3
[ Boiling Point ]:
88-89ºC43 mm Hg(lit.)
[ Molecular Formula ]:
C9H21N3
[ Molecular Weight ]:
171.28300
[ Flash Point ]:
65ºC
[ Exact Mass ]:
171.17400
[ PSA ]:
18.84000
[ LogP ]:
1.26410
[ Vapour Pressure ]:
0.0167mmHg at 25°C
[ Index of Refraction ]:
n20/D 1.457
MSDS
Safety Information
[ Symbol ]:
GHS05, GHS07
[ Signal Word ]:
Danger
[ Hazard Statements ]:
H302-H314
[ Precautionary Statements ]:
P280-P305 + P351 + P338-P310
[ Personal Protective Equipment ]:
Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter
[ Hazard Codes ]:
C: Corrosive;
[ Risk Phrases ]:
22-34
[ Safety Phrases ]:
26-36/37/39-45
[ RIDADR ]:
UN 3267 8/PG 2
[ WGK Germany ]:
3
[ HS Code ]:
2925290090
Customs
[ HS Code ]: 2925290090
[ Summary ]:
2925290090 other imines and their derivatives; salts thereof。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。MFN tariff:6.5%。General tariff:30.0%
Articles
Org. Lett. 5(7) , 1155-8, (2003)
[reaction: see text] Electron-rich dinaphthyl ethers were synthesized by S(N)Ar reactions between naphthols and activated fluoronaphthalenes. 2-tert-Butyl-1,1,3,3-tetramethylguanidine (Barton's base) ...
D.H.R. Barton et al.Organic Synth. 74 , 103, (1997)