4-chlorocinnamonitrile

Names

[ Name ]:
4-chlorocinnamonitrile

[Synonym ]:
4-Chlorobenzeneacrylonitrile
p-chloro-cinnamonitril
P-CHLOROCINNAMONITRILE
MFCD00001932
EINECS 249-025-0
4-chlorocinnamonitrile,mixture of cis and T

Chemical & Physical Properties

[ Density]:
1.205g/cm3

[ Boiling Point ]:
293.9ºC at 760mmHg

[ Melting Point ]:
55-70ºC(lit.)

[ Molecular Formula ]:
C₉H₆ClN

[ Molecular Weight ]:
163.60400

[ Flash Point ]:
130.9ºC

[ Exact Mass ]:
163.01900

[ PSA ]:
23.79000

[ LogP ]:
2.87678

[ Vapour Pressure ]:
0.00168mmHg at 25°C

[ Index of Refraction ]:
1.608

MSDS

Click to get detail MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :: GE1457900

CHEMICAL NAME :: Cinnamonitrile, p-chloro-

CAS REGISTRY NUMBER :: 28446-72-2

LAST UPDATED :: 199612

DATA ITEMS CITED :: 1

MOLECULAR FORMULA :: C9-H6-Cl-N

MOLECULAR WEIGHT :: 163.61

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Intraperitoneal

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 78 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: RPTOAN Russian Pharmacology and Toxicology (English Translation). Translation of FATOAO. (Euromed Pub., 33, Woodlands Rd., Surbiton, Surrey, UK) V.30- 1967- Volume(issue)/page/year: 46,174,1983

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H302 + H312 + H332-H315-H319-H335

[ Precautionary Statements ]:
P261-P280-P305 + P351 + P338

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves

[ Hazard Codes ]:
Xn: Harmful;

[ Risk Phrases ]:
20/21/22-36/37/38

[ Safety Phrases ]:
26-37/39

[ RIDADR ]:
NONH for all modes of transport

[ RTECS ]:
GE1457900

[ HS Code ]:
2926909090

Precursor & DownStream

Precursor

DownStream

Customs

[ HS Code ]: 2926909090

[ Summary ]:
HS:2926909090 other nitrile-function compounds VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:30.0%

Articles

Diethoxymethylphosphonites and phosphinates. Intermediates for thesynthesis of a, ß-and X aminoalkylphosphonous acids. Dingwalla JG, et al.

Tetrahedron 45(12) , 3787-3808, (1989)

Radical homo-and copolymerization of ring-substituted trans-and cis-cinnamonitriles. Tanaka H, et al.

Makromol. Chem., Rapid Commun. 14(10) , 649-655, (1993)