1-Cyclohexen-1-yl trifluoromethanesulfonate

Names

[ Name ]:
1-Cyclohexen-1-yl trifluoromethanesulfonate

[Synonym ]:
Cyclohexenyl triflate
Methanesulfonic acid, 1,1,1-trifluoro-, 1-cyclohexen-1-yl ester
1-Cyclohexenyl trifluoromethanesulfonate
trifluoromethanesulfonic acid cyclohex-1-enyl ester
Cyclohex-1-en-1-yl triflate
1-Cyclohexen-1-yl trifluoromethanesulfonate
1-cyclohexenyl triflate
trifluoromethanesulfonic acid 1-cyclohexenyl ester
cyclohex-1-en-1-yl trifluoromethanesulfonate
O-trifluoromethylsulfonyl-1-cyclohexenol
MFCD06411281
cyclohex-1-en-1-yl trifluoromethane sulfonate

Chemical & Physical Properties

[ Density]:
1.4±0.1 g/cm3

[ Boiling Point ]:
244.6±40.0 °C at 760 mmHg

[ Molecular Formula ]:
C₇H₉F₃O₃S

[ Molecular Weight ]:
230.205

[ Flash Point ]:
101.7±27.3 °C

[ Exact Mass ]:
230.022446

[ PSA ]:
51.75000

[ LogP ]:
3.45

[ Vapour Pressure ]:
0.0±0.5 mmHg at 25°C

[ Index of Refraction ]:
1.446

[ Storage condition ]:
2-8℃

Safety Information

[ Personal Protective Equipment ]:
Eyeshields;Gloves;half-mask respirator (US);multi-purpose combination respirator cartridge (US)

[ RIDADR ]:
NA 1993 / PGIII

[ WGK Germany ]:
3

[ HS Code ]:
2906199090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

DownStream

Customs

[ HS Code ]: 2906199090

[ Summary ]:
2906199090. cyclanic, cyclenic or cyclotherpenic alcohols. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:5.5%. General tariff:30.0%

Articles

The palladium-catalyzed trifluoromethylation of vinyl sulfonates.

Org. Lett. 13(24) , 6552-5, (2011)

A method for the palladium-catalyzed trifluoromethylation of cyclohexenyl sulfonates has been developed. Various cyclohexenyl triflates and nonaflates underwent trifluoromethylation under mild reactio...

Proline derived phosphine-oxazoline ligands in the asymmetric Heck reaction. Gilbertson SR, et al.

Tetrahedron Lett. 42(3) , 365-368, (2001)