4-Bromo-3-methyl-anisole
Names
[ CAS No. ]:
27060-75-9
[ Name ]:
4-Bromo-3-methyl-anisole
[Synonym ]:
1-Bromo-4-methoxy-2-methylbenzene
2-Bromo-5-methoxytoluene (BMA)
Benzene,1-bromo-4-methoxy-2-methyl
2-BroMo-5-Methoxytoluene
4-Bromo-3-methylphenyl methyl ether
4-Bromo-3-methyl-anisole
1-brom-4-methoxy-2-methylbenzol
Benzene, 1-bromo-4-methoxy-2-methyl-
1-bromo-4-methoxy-2-methyl-benzene
2-methyl-4-methoxybromobenzene
MFCD00060687
4-Bromo-3-methylanisole
4-methoxy-2-methylphenyl bromide
4-bromo-1-methoxy-3-methylbenzene
Chemical & Physical Properties
[ Density]:
1.4±0.1 g/cm3
[ Boiling Point ]:
235.3±20.0 °C at 760 mmHg
[ Molecular Formula ]:
C8H9BrO
[ Molecular Weight ]:
201.061
[ Flash Point ]:
105.3±7.8 °C
[ Exact Mass ]:
199.983673
[ PSA ]:
9.23000
[ LogP ]:
3.63
[ Vapour Pressure ]:
0.1±0.4 mmHg at 25°C
[ Index of Refraction ]:
1.535
MSDS
Safety Information
[ Personal Protective Equipment ]:
Eyeshields;Gloves
[ Hazard Codes ]:
Xi: Irritant;
[ Safety Phrases ]:
S24/25
[ RIDADR ]:
NONH for all modes of transport
[ WGK Germany ]:
3
[ HS Code ]:
2909309090
Synthetic Route
Customs
[ HS Code ]: 2909309090
[ Summary ]:
2909309090 other aromatic ethers and their halogenated, sulphonated, nitrated or nitrosated derivatives VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:5.5% General tariff:30.0%
Articles
Org. Lett. 6 , 225-228, (2004)
[reaction: see text] Sterically demanding, sulfonated arylphosphines TXPTS and TMAPTS have been applied to the aqueous-phase Heck and Suzuki coupling of aryl bromides. TXPTS provides good yields of He...
Discovery of orally active nonpeptide vitronectin receptor antagonists based on a 2-benzazepine Gly-Asp mimetic.J. Med. Chem. 43.1 , 22-26, (2000)
A concise synthesis of the naphthoic acid component of neocarzinostatin chromophore featuring a new photocyclization reaction. Myers et al.
Tetrahedron Lett. 37.5 , 587-590, (1996)