Ethanone,2,2-dichloro-1-phenyl-

Names

[ Name ]:
Ethanone,2,2-dichloro-1-phenyl-

[Synonym ]:
PHENACYLIDENE CHLORIDE
1,1-Dichloroacetophenone
2,2-dichloro-1-phenylethan-1-one
MFCD00000844
2,2-dichloro-acetophenon
Dichloroacetylbenzene
A A-DICHLOROACETOPHENONE
Acetophenone,2,2-dichloro
EINECS 202-783-6

Chemical & Physical Properties

[ Density]:
1.34 g/mL at 25 °C(lit.)

[ Boiling Point ]:
132-134 °C13 mm Hg(lit.)

[ Melting Point ]:
20-21 °C(lit.)

[ Molecular Formula ]:
C₈H₆Cl₂O

[ Molecular Weight ]:
189.03900

[ Flash Point ]:
>230 °F

[ Exact Mass ]:
187.98000

[ PSA ]:
17.07000

[ LogP ]:
2.67300

[ Vapour Pressure ]:
0.0194mmHg at 25°C

[ Index of Refraction ]:
n20/D 1.5686(lit.)

MSDS

Click to get detail MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :: AM7175000

CHEMICAL NAME :: Acetophenone, 2,2-dichloro-

CAS REGISTRY NUMBER :: 2648-61-5

BEILSTEIN REFERENCE NO. :: 1864186

LAST UPDATED :: 199701

DATA ITEMS CITED :: 3

MOLECULAR FORMULA :: C8-H6-Cl2-O

MOLECULAR WEIGHT :: 189.04

WISWESSER LINE NOTATION :: GYGVR

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: LCLo - Lowest published lethal concentration

ROUTE OF EXPOSURE :: Inhalation

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 940 mg/m3/10M

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: NDRC** National Defense Research Committee, Office of Scientific Research and Development, Progress Report. Volume(issue)/page/year: NDCrc-132,AUG1942

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Intravenous

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 100 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: CSLNX* U.S. Army Armament Research & Development Command, Chemical Systems Laboratory, NIOSH Exchange Chemicals. (Aberdeen Proving Ground, MD 21010) Volume(issue)/page/year: NX#03021

Safety Information

[ Hazard Codes ]:
Xi:Irritant;

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
S26-S27-S28-S36/37/39

[ RIDADR ]:
UN 2810 6.1/PG 2

[ WGK Germany ]:
3

[ RTECS ]:
AM7175000

[ Packaging Group ]:
II

[ HS Code ]:
2914700090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

DownStream

Customs

[ HS Code ]: 2914700090

[ Summary ]:
HS: 2914700090 halogenated, sulphonated, nitrated or nitrosated derivatives of ketones and quinones, whether or not with other oxygen function Tax rebate rate:9.0% Supervision conditions:none VAT:17.0% MFN tariff:5.5% General tariff:30.0%