tBuMePhos
Names
[ CAS No. ]:
255837-19-5
[ Name ]:
tBuMePhos
[Synonym ]:
2-Di-tert.-buthyl-phosphino-2`-methylbiphenyl
t-Butyl MePhos
Phosphine, bis(1,1-dimethylethyl)(2'-methyl[1,1'-biphenyl]-2-yl)-
2-Di-tert-butylphosphino-2'-methylbiphenyl
2-(DI-T-BUTYLPHOSPHINO)-2'-METHYLBIPHENYL
t-Butyl MePhos tBuMePhos
Di-tert-butyl(2'-methylbiphenyl-2-yl)phosphine
tBuMePhos
2-(Di-tert-butylphosphino)-2‘-methylbiphenyl
Di-tert-butyl(2'-methyl-[1,1'-biphenyl]-2-yl)phosphine
MFCD03453047
(2'-Methyl-2-biphenylyl)[bis(2-methyl-2-propanyl)]phosphine
2-(Di-tert-butylphosphino)-2'-methylbiphenyl
Chemical & Physical Properties
[ Boiling Point ]:
408.0±24.0 °C at 760 mmHg
[ Melting Point ]:
91-93ºC
[ Molecular Formula ]:
C21H29P
[ Molecular Weight ]:
312.429
[ Flash Point ]:
211.7±29.2 °C
[ Exact Mass ]:
312.200684
[ PSA ]:
13.59000
[ LogP ]:
7.24
[ Vapour Pressure ]:
0.0±0.9 mmHg at 25°C
MSDS
Safety Information
[ Hazard Codes ]:
Xi: Irritant;
[ Risk Phrases ]:
R36/37/38
[ Safety Phrases ]:
37/39-26
[ RIDADR ]:
NONH for all modes of transport
[ HS Code ]:
2931900090
Customs
[ HS Code ]: 2931900090
[ Summary ]:
2931900090. other organo-inorganic compounds. VAT:17.0%. Tax rebate rate:13.0%. Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward). MFN tariff:6.5%. General tariff:30.0%
Articles
Acc. Chem. Res. 41 , 1461, (2008)
The cores of many types of polymers, ligands, natural products, and pharmaceuticals contain biaryl or substituted aromatic structures, and efficient methods of synthesizing these structures are crucia...
Biaryl phosphane ligands in palladium-catalyzed amination.Angew. Chem. Int. Ed. Engl. 47 , 6338, (2008)
Palladium-catalyzed amination reactions of aryl halides have undergone rapid development in the last 12 years, largely driven by the implementation of new classes of ligands. Biaryl phosphanes have pr...
Dialkylbiaryl Phosphines in Pd-Catalyzed Amination: A User's Guide.Chem. Sci. 2 , 27, (2011)
Dialkylbiaryl phosphines are a valuable class of ligand for Pd-catalyzed amination reactions and have been applied in a range of contexts. This review attempts to aid the reader in the selection of th...